4732-66-5Relevant articles and documents
Synthesis and X-ray structure of N-phenyl phenylglyoxamide
Boryczka, Stanislaw,Suwinska, Kinga,Le Guillanton, Georges,Do, Quang Tho,Elothmani, Driss
, p. 555 - 560 (1998)
The title compound (C14H11NO2) is monoclinic with a = 13.579(2), b = 5.297(1), c = 16.455(2) A, β = 98.11(2)°, Z = 4, and space group P21/n. The significant structural features lie in the two carbonyl groups of the glyoxamide which are oriented antiperiplanar to each other [-163.6(3)°]. The central bond C(1)-C(2) is 1.545(4) A. The observed conformation is stabilized by intramolecular hydrogen bonds.
Desulfurizing agent for thioamides
Polushina,Zavarzin,Krayushkin,Rodionova,Yarovenko
, p. 383 - 385 (2021/03/03)
Thioamides treated with thionyl chloride in an ionic liquid were successfully converted into amides.
Synthetic method of alpha-keto amide compound
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Paragraph 0069-0074, (2020/09/23)
The invention discloses a synthesis method of an alpha-keto amide compound, which comprises the following steps: mixing a benzoyl azide compound as shown in a chemical formula I with a benzoyl formicacid compound as shown in a chemical formula II, and reacting to obtain an alpha-keto amide compound as shown in a chemical formula III; in the formula, R1 is a monosubstituted or polysubstituted group on a benzene ring; R2 is a group that is not H; the synthesis method can be used for efficiently synthesizing the functionalized alpha-ketoamide compound, has the advantages of simple synthesis steps, safety in operation, good compatibility of the synthesis method to functional groups and high atom economy, and is easy for industrial synthesis.