4802-43-1

Basic information

• Product Name: Bicyclo[3.2.1]oct-3-en-2-ol, exo-
• CAS NO: 4802-43-1
• Molecular Formula: C8H12O
• Mol File: 4802-43-1.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Bicyclo[3.2.1]oct-3-en-2-ol, exo-(CAS DataBase Reference)
• NIST Chemistry Reference: Bicyclo[3.2.1]oct-3-en-2-ol, exo-(4802-43-1)
• EPA Substance Registry System: Bicyclo[3.2.1]oct-3-en-2-ol, exo-(4802-43-1)

Safety Data

• Hazardous Substances Data: 4802-43-1(Hazardous Substances Data)

Upstream product

• 20507-56-6 bicyclo<2.2.2>oct-5-ene-2-exo-carboxylic acid 
• 3212-76-8 exo-(axial)-Bicyclo<3.2.1>octen-(3)-yl-(2)-p-nitro-benzoat 
• 3212-76-8 dl-endo-Bicyclo<3.2.1>oct-3-en-2yl p-Nitrobenzoat 
• 823-02-9 bicyclo[3.2.1]oct-2-ene 
• 139070-08-9 Bicyclo<3.2.1>oct-2-en-6-on-(p-toluolsulfonylhydrazon) 
• 4802-37-3 Acetic acid (1R,5S)-bicyclo[3.2.1]oct-3-en-2-yl ester 
• 80976-66-5 exo-3-chloro-4-hydroxybicyclo<3.2.1>oct-2-ene 
• 39762-77-1 endo-bicyclo<3.2.1.>oct-3-en-2-yl acetate 
• 3212-77-9 2-Oxobicyclo<3.2.1>oct-3-ene 
• 4802-37-3 exo-bicyclo<3.2.1.>oct-3-en-2-yl acetate 
• 931-64-6 bicyclo<2.2.2>oct-2-ene 
• 498-66-8 norborn-2-ene 
• 917-54-4 methyllithium 
• 823-02-9 bicyclo[3.2.1]oct-2-ene 

Downstream Products

• 1965-38-4 Bicyclo<3.2.1>octan-exo-2-ol 
• 4802-43-1 exo-bicyclo<3.2.1>oct-3-en-2-ol 
• 32222-49-4 endo-bicyclo<3.2.1>oct-3-en-2-ol 
• 80976-45-0 anti-bicyclo<3.2.1>octa-2,6-dien-4-one p-toluenesulfonylhydrazone 
• 80976-48-3 bicyclo<3.2.1>oct-3-en-2-one p-toluenesulfonylhydrazone 
• 88158-52-5 exo-bicyclo<3.2.1>oct-3-en-2-yl mesitoate 

Relevant articles and documents

Rearrangement of Bicyclooct-2-en-6-yl and Benzobicyclooctenyl Cations

The ketones 9, 27, and 51 were prepared by modified or novel routes.The analogous tosylhydrazones 10, 28, and 52 were photolyzed in 0.5 N NaOH to generate the carbocations 15, 34, and 53, respectively, by way of diazonium precursors. 2,3-Unsaturati

Alkylation of Allylic Derivatives. 8. Regio- and Stereochemistry of Alkylation of Allylic Carboxylates with Lithium Methylcyanocuprate

Alkylation of 5-methyl-2-cyclohexenyl acetate (1-OAc) with lithium methylcyanocuprate (LiCu(CN)Me) is regiospecific (>90 percent excess γ-alkylation) and sterospecific (>95 percent anti alkylation).In the bicyclooct-3-en-2-yl system (3), alkylation is stereoselective (both isomers give exo alkylation) and regiospecific (excess γ-alkylation).Alkylation of trans-α-methyl-γ-mesitylallyl acetate (8-OAc) with LiCu(CN)Me gives 57 percent α- and 43 percent γ-alkylation as compared to >97 percent α-alkylation with LiCuMe2.Mechanistic implications are discussed.