5042-53-5 Usage
Description
(PHENYLTHIO)PROPANONE, also known as 1-(Phenylthio)propan-2-one, is an organic compound with the chemical formula C9H10OS. It is a colorless to pale yellow liquid with a distinctive odor. The molecule consists of a propyl ketone backbone with a phenylthio group attached to the carbonyl carbon. (PHENYLTHIO)PROPANONE is known for its reactivity and versatility in organic synthesis.
Uses
Used in Chemical Synthesis:
(PHENYLTHIO)PROPANONE is used as a reagent for the preparation of (oxo-phenylsulfanyl)benzoates. It serves as a key intermediate in the synthesis of various organic compounds, particularly those containing the phenylsulfanyl group. The reactivity of the compound allows for the formation of a wide range of derivatives, making it a valuable building block in organic chemistry.
Used in Pharmaceutical Industry:
(PHENYLTHIO)PROPANONE is used as a starting material for the synthesis of pharmaceutical compounds. Its unique structure and reactivity enable the development of new drugs with potential therapeutic applications. (PHENYLTHIO)PROPANONE can be modified and functionalized to create novel molecules with specific biological activities, contributing to the discovery of new medications.
Used in Agrochemical Industry:
(PHENYLTHIO)PROPANONE is used as a precursor in the synthesis of agrochemicals, such as pesticides and herbicides. Its ability to form a variety of derivatives makes it a valuable component in the development of new and effective crop protection agents. (PHENYLTHIO)PROPANONE's reactivity allows for the creation of molecules with targeted modes of action, improving the efficiency and selectivity of these agrochemicals.
Used in Material Science:
(PHENYLTHIO)PROPANONE is used as a building block in the synthesis of novel materials with unique properties. Its incorporation into polymers, for example, can lead to the development of materials with enhanced thermal stability, mechanical strength, or electrical conductivity. (PHENYLTHIO)PROPANONE's versatility in organic synthesis makes it a valuable component in the creation of advanced materials for various applications.
Synthesis Reference(s)
Tetrahedron Letters, 23, p. 2509, 1982 DOI: 10.1016/S0040-4039(00)87382-7
Check Digit Verification of cas no
The CAS Registry Mumber 5042-53-5 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 5,0,4 and 2 respectively; the second part has 2 digits, 5 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 5042-53:
(6*5)+(5*0)+(4*4)+(3*2)+(2*5)+(1*3)=65
65 % 10 = 5
So 5042-53-5 is a valid CAS Registry Number.
InChI:InChI=1/C9H10OS/c1-8(10)7-11-9-5-3-2-4-6-9/h2-6H,7H2,1H3
5042-53-5Relevant articles and documents
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Knight et al.
, p. 1893 (1944)
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Air-stable binuclear Titanium(IV) salophen perfluorobutanesulfonate with zinc power catalytic system and its application to C–S and C–Se bond formation
Wang, Lingxiao,Qiao, Jie,Wei, Jiancong,Liang, Zhiwu,Xu, Xinhua,Li, Ningbo
, (2020/01/08)
An air-stable μ-oxo-bridged binuclear Lewis acid of titanium(IV) salophen perfluorobutanesulfonate [{Ti(salophen)H2O}2O][OSO2C4F9]2 (1) was successfully synthesized by the reaction of TiIV(salophen)Cl2 with AgOSO2C4F9 and characterized by techniques such as IR, NMR and HRMS. This complex was stable open to air over a year, and exhibited good thermal stability and high solubility in polar organic solvents. The complex also had relatively strong acidity with a strength of 0.8 Ho ≤ 3.3, and showed high catalytic efficiency towards various C–S and C–Se bond formations in the presence of zinc power. This catalytic system affords a mild and efficient approach to synthesis of thio- and selenoesters, α-arylthio- and seleno-carbonyl compounds, and thio- and selenoethers.
Synthesis of α-arylthioacetones using TEMPO as the: C 3 synthon via a reaction cascade of sequential oxidation, skeletal rearrangement and C-S bond formation
Zou, Jiao-Xia,Jiang, Yi,Lei, Shuai,Yin, Gao-Feng,Hu, Xiao-Ling,Zhao, Quan-Yi,Wang, Zhen
supporting information, p. 2341 - 2345 (2019/03/07)
Here, we present an unprecedented pathway to α-sulfenylated carbonyl compounds from commercially available thiols and universally employed TEMPO and its analogues, which act as C3 synthons through skeletal rearrangement under simple and metal-f
