53314-75-3

Basic information

• Product Name: Benzyl-δ-(methoxycarbonyl)-γ-oxovalerate
• CAS NO: 53314-75-3
• Molecular Weight: 264.278
• Mol File: 53314-75-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Benzyl-δ-(methoxycarbonyl)-γ-oxovalerate(CAS DataBase Reference)
• NIST Chemistry Reference: Benzyl-δ-(methoxycarbonyl)-γ-oxovalerate(53314-75-3)
• EPA Substance Registry System: Benzyl-δ-(methoxycarbonyl)-γ-oxovalerate(53314-75-3)

Safety Data

• Hazardous Substances Data: 53314-75-3(Hazardous Substances Data)

Upstream product

• 77902-95-5 succinic acid monomethylester pyrrolidine amide 
• 77902-88-6 1-<<β-(Methoxycarbonyl)thio>propionyl>pyrrolidine 
• 5437-45-6 Benzyl bromoacetate 

Downstream Products

• 74839-04-6 2-[(E)-Hydroxyimino]-3-oxo-hexanedioic acid 1-benzyl ester 6-methyl ester 
• 53365-81-4 3-(2-methoxycarbonyl-ethyl)-5-methyl-pyrrole-2,4-dicarboxylic acid 2-benzyl ester 
• 53365-80-3 Methyl 2-(benzyloxycarbonyl)-4-(tert-butoxycarbonyl)-5-methylpyrrole-3-propionate 
• 183061-79-2 C₄₄H₅₁N₃O₁₇ 
• 135100-99-1 (S)-4-<5-Benzyloxycarbonyl-3-(2-methoxycarbonylethyl)-4-(methoxycarbonylmethyl)pyrrol-2-ylmethyl>-2,8-bis(2-methoxycarbonylethyl)-3,7-bis(methoxycarbonylmethyl)-9-(2,2,2-tribromoethoxycarbonyl)-4,5-dihydrodipyrrin-1(10H)-one 
• 135100-95-7 (R)-4-<5-Benzyloxycarbonyl-3-(2-methoxycarbonylethyl)-4-(methoxycarbonylmethyl)pyrrol-2-ylmethyl>-2,8-bis(2-methoxycarbonylethyl)-3,7-bis(methoxycarbonylmethyl)-9-(2,2,2-tribromoethoxycarbonyl)-4,5-dihydrodipyrrin-1(10H)-one 
• 183005-13-2 4-Iodo-3-(2-methoxycarbonyl-ethyl)-5-methyl-1H-pyrrole-2-carboxylic acid benzyl ester 
• 183005-14-3 4-Carboxymethyl-3-(2-methoxycarbonyl-ethyl)-5-methyl-1H-pyrrole-2-carboxylic acid benzyl ester 
• 183005-06-3 3-(2-Methoxycarbonyl-ethyl)-5-methyl-4-(2-trimethylsilanyl-ethoxycarbonylmethyl)-1H-pyrrole-2-carboxylic acid benzyl ester 
• 183005-15-4 5-Acetoxymethyl-3-(2-methoxycarbonyl-ethyl)-4-(2-trimethylsilanyl-ethoxycarbonylmethyl)-1H-pyrrole-2-carboxylic acid benzyl ester 
• 183005-05-2 5-[3-Carboxymethyl-4-(2-methoxycarbonyl-ethyl)-2-methyl-5-oxo-2,5-dihydro-1H-pyrrol-2-ylmethyl]-4-(2-methoxycarbonyl-ethyl)-3-methoxycarbonylmethyl-1H-pyrrole-2-carboxylic acid benzyl ester 
• 183005-10-9 4-(2-Methoxycarbonyl-ethyl)-5-[4-(2-methoxycarbonyl-ethyl)-2-methyl-5-oxo-3-(2-trimethylsilanyl-ethoxycarbonylmethyl)-2,5-dihydro-1H-pyrrol-2-ylmethyl]-3-methoxycarbonylmethyl-1H-pyrrole-2-carboxylic acid benzyl ester 
• 135100-96-8 4-[5-Benzyloxycarbonyl-3-(2-methoxycarbonylethyl)-4-methoxycarbonylmethylpyrrol-2-ylmethyl]-7-carboxymethyl-2,8-bis(2-methoxycarbonylethyl)-9-(2,2,2-tribromoethoxycarbonyl)-3-(2-trimethylsilylethoxycarbonylmethyl)-4,5-dihydrodipyrrin-1(10H)-one 
• 135100-97-9 4-[5-Benzyloxycarbonyl-3-(2-methoxycarbonylethyl)-4-methoxycarbonylmethylpyrrol-2-ylmethyl]-2,8-bis(2-methoxycarbonylethyl)-7-methoxycarbonylmethyl-9-(2,2,2-tribromoethoxycarbonyl)-3-(2-trimethylsilylethoxycarbonylmethyl)-4,5-dihydrodipyrrin-1(10H)-one 

Relevant articles and documents

Versatile β-Keto Ester and β-Keto Nitrile Synthesis through Sulfide Contraction.

A versatile and efficient synthesis for various β-keto esters, including those which are α substituted, is described.The α-thio iminium salt prepared from a thioamide and a primary or secondary alkylating agent is subjected to sulfur extrusion upon addition of base and a phosphine thiophile, and the result is an enamino ester which may be hydrolyzed to the desired β-keto ester.The method is also applicable to the preparation of various substituted β-keto nitriles.