6136-66-9

Basic information

• Product Name: 4-IODOBENZOPHENONE
• Synonyms: 4-IODOBENZOPHENONE
• CAS NO: 6136-66-9
• Molecular Formula: C₁₃H₉IO
• Molecular Weight: 308.11
• Mol File: 6136-66-9.mol
• Article Data: 31

Chemical Properties

• Melting Point: 97-99°C
• Boiling Point: 366.6 °C at 760 mmHg
• Flash Point: 175.5 °C
• Appearance: /
• Density: 1.624 g/cm³
• Vapor Pressure: 1.45E-05mmHg at 25°C
• Refractive Index: 1.647
• Storage Temp.: Keep in dark place,Sealed in dry,Room Temperature
• CAS DataBase Reference: 4-IODOBENZOPHENONE(CAS DataBase Reference)
• NIST Chemistry Reference: 4-IODOBENZOPHENONE(6136-66-9)
• EPA Substance Registry System: 4-IODOBENZOPHENONE(6136-66-9)

Safety Data

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36/37/39
• HazardClass: IRRITANT
• Hazardous Substances Data: 6136-66-9(Hazardous Substances Data)

Usage

General Description

4-Iodobenzophenone is a chemical compound with the molecular formula C13H9IO. It is a pale yellow solid that is soluble in organic solvents and is commonly used as a building block in the synthesis of various organic compounds. 4-Iodobenzophenone is used in the production of pharmaceuticals, dyes, and other organic chemicals. It is also used as a photoinitiator in the formulation of UV-curable inks and coatings. 4-IODOBENZOPHENONE is considered to be a potential environmental hazard and should be handled with care due to its toxic and irritant properties. Additionally, 4-Iodobenzophenone is regulated as a hazardous substance in some jurisdictions and should be used with appropriate safety precautions and protective equipment.

InChI:InChI=1/C13H9IO/c14-12-8-6-11(7-9-12)13(15)10-4-2-1-3-5-10/h1-9H

Upstream product

• 172483-72-6 4-iodobenzhydrol 
• 106480-53-9 4-dichloroiodanyl-benzophenone 
• 591-50-4 iodobenzene 
• 98-88-4 benzoyl chloride 
• 201230-82-2 carbon monoxide 
• 934-56-5 trimethyl(phenyl)stannane 
• 1514-50-7 4-iodobenzenediazonium tetrafluoroborate 
• 1137-41-3 (4-aminophenyl)(phenyl)methanone 
• 71-43-2 benzene 
• 64-19-7 acetic acid 
• 15164-44-0 p-(iodophenyl)carboxaldehyde 
• 624-38-4 para-diiodobenzene 
• 90-90-4 (4-bromophenyl)(phenyl)methanone 
• 35444-94-1 1-benzyl-4-iodobenzene 

Downstream Products

• 33090-29-8 4,4'-dibenzoyl-1,1'-biphenyl 
• 172483-72-6 4-iodobenzhydrol 
• 861602-18-8 1,2-bis-(4-iodo-phenyl)-1,2-diphenyl-ethane-1,2-diol 
• 106480-53-9 4-dichloroiodanyl-benzophenone 
• 857816-20-7 3-hydroxy-3-(4-iodo-phenyl)-3-phenyl-propionic acid ethyl ester 
• 3016-97-5 1,4-dibenzoylbenzene 
• 18220-90-1 4-ethylbenzophenone 
• 53689-84-2 4-acetylbenzophenone 
• 119754-14-2 4-(4-benzoylphenyl)-2-methyl-3-butyn-2-ol 
• 134-84-9 4-Methylbenzophenone 
• 35444-94-1 1-benzyl-4-iodobenzene 
• 59922-54-2 4-benzoylphenyl radical 
• 119-61-9 benzophenone 
• 134-85-0 4-chlorobenzophenone 

Relevant articles and documents

Photo-induced oxidative cleavage of C-C double bonds of olefins in water

The carbonyl compounds, synthesized by the oxidative cleavage of their corresponding olefins, are of great significance in organic synthesis, especially aryl ketones. We have developed a gentle and effective protocol, using acid red 94 as the organic metal-free photocatalyst, O2 as the oxidant, and water as the solvent. Under visible light irradiation, aryl ketone derivatives were obtained in moderate to excellent yields, showing good economic and environmental advantages.

Aryl aldiketone and synthesis method thereof

The invention discloses an aryl aldehyde ketone and a synthesis method thereof, wherein an aryl aldehyde is synthesized from cheap olefin as a raw material. A commercially available inexpensive olefin is used as a raw material, ether is used as an additive, molecular oxygen serves as a sole oxidizing agent, water is used as a solvent, and the aldehyde and ketone are synthesized by column chromatography under a photocatalytic condition. The invention has the advantages of mild reaction conditions, green and environmental protection, simple experimental operation, good reaction selectivity, high product yield and the like.

Hydrogen-Bond-Donor Solvents Enable Catalyst-Free (Radio)-Halogenation and Deuteration of Organoborons

A hydrogen bond donor solvent assisted (radio)halogenation and deuteration of organoborons has been developed. The reactions exhibited high functional group tolerance and needed only an ambient atmosphere. Most importantly, compared to literature methods, our conditions are more consistent with the principals of green chemistry (e.g., metal-free, strong oxidant-free, more straightforward conditions).