626-20-0

Basic information

• Product Name: 3-VINYLANISOLE 97
• Synonyms: 3-VINYLANISOLE 97;3-Methoxystyrene, (Stabilized with 4-t-Butylcatechol);1-Ethenyl-3-methoxybenzene;1-Vinyl-3-methoxybenzene;m-Methoxystyrene;3-Vinylanisole 97%;1-Methoxy-3-vinylbenzene
• CAS NO: 626-20-0
• Molecular Formula: C₉H₁₀O
• Molecular Weight: 134.18
• Product Categories: Acyclic;Alkenes;Organic Building Blocks
• Mol File: 626-20-0.mol
• Article Data: 71

Chemical Properties

• Boiling Point: 204-205 °C(lit.)
• Flash Point: 172 °F
• Appearance: /
• Density: 0.967 g/mL at 25 °C(lit.)
• Refractive Index: n20/D 1.5540(lit.)
• Storage Temp.: 2-8°C
• CAS DataBase Reference: 3-VINYLANISOLE 97(CAS DataBase Reference)
• NIST Chemistry Reference: 3-VINYLANISOLE 97(626-20-0)
• EPA Substance Registry System: 3-VINYLANISOLE 97(626-20-0)

Safety Data

• WGK Germany: 3
• Hazardous Substances Data: 626-20-0(Hazardous Substances Data)

Usage

General Description

Inhibited with 1000ppm p-tert-butylcatechol

Upstream product

• 5020-41-7 2-(3-methoxyphenyl)-ethanol 
• 6099-04-3 trans-3-methoxycinnamic acid 
• 620-18-8 3-hydroxystyrene 
• 77-78-1 dimethyl sulfate 
• 611-70-1 phenyl isopropyl ketone 
• 6099-04-3 3-methoxycinnamic acid 
• 20387-28-4 Bis-(m-methoxy-benzyl-acetyl)-peroxid 
• 25226-97-5 3-methoxyphenethyl iodide 
• 20826-85-1 (+)-tricyclo<3.3.0.0^2.8>octan-3-one 
• 58114-05-9 1-chloro-1-(3'-methoxyphenyl)ethane 
• 74-85-1 ethene 
• 1711-05-3 m-anisoyl chloride 
• 917-54-4 methyllithium 
• 591-31-1 3-methoxy-benzaldehyde 

Downstream Products

• 10568-38-4 3-ethylanisole 
• 37728-89-5 1-(1,2-dibromoethyl)-3-methoxybenzene 
• 65038-17-7 1-(2,2-dibromocyclopropyl)-3-methoxybenzene 
• 39791-81-6 5-(3-methoxy-phenyl)-2-[1-(3-methoxy-phenyl)-2-nitro-ethoxy]-3,3-dinitro-isoxazolidine 
• 83716-64-7 4-(3-methoxy-phenyl)-azetidin-2-one 
• 83716-67-0 (E)-3-(3-methoxyphenyl)acrylamide 
• 60235-09-8 1-bromo-6-(m-methoxyphenyl)hexan-3-one 
• 96728-32-4 cis-1-(m-methoxyphenyl)-2-(β-bromopropionyl)cyclopropane 
• 96728-31-3 trans-1-(m-methoxyphenyl)-2-(β-bromopropionyl)cyclopropane 
• 132259-66-6 (7R*)-7-(3-Methoxyphenyl)-3,3-dimethylbicyclo<2.2.2>oct-5-en-2-on 
• 40463-26-1 5-(m-Methoxyphenyl)-2-methyl-1-penten 
• 74672-09-6 4-(m-Methoxyphenyl)-2-methyl-1-penten 
• 96728-33-5 trans-1-(m-methoxyphenyl)-2-<β-(2-methyl-1,3-dioxocyclopent-2-yl)propionyl>cyclopropane 
• 96728-34-6 cis-1-(m-methoxyphenyl)-2-<β-(2-methyl-1,3-dioxocyclopent-2-yl)propionyl>cyclopropane 

Relevant articles and documents

Nickel-Catalyzed Enantioselective Hydroboration of Vinylarenes

The enantioselective hydroboration of vinylarenes catalyzed by a chiral, nonracemic nickel catalyst is presented as a facile method for generating chiral benzylic boronate esters. Various vinylarenes react with bis(pinacolato)diboron (B2pin2) in the presence of MeOH as a hydride source to form chiral boronate esters in up to 92% yield with up to 94% ee. The use of anhydrous Me4NF to activate B2pin2 is crucial for ensuring fast transmetalation to achieve high enantioselectivities.

Nickel-Catalyzed Reductive Cross-Coupling of Aryl Bromides with Vinyl Acetate in Dimethyl Isosorbide as a Sustainable Solvent

A nickel-catalyzed reductive cross-coupling has been achieved using (hetero)aryl bromides and vinyl acetate as the coupling partners. This mild, applicable method provides a reliable access to a variety of vinyl arenes, heteroarenes, and benzoheterocycles, which should expand the chemical space of precursors to fine chemicals and polymers. Importantly, a sustainable solvent, dimethyl isosorbide, is used, making this protocol more attractive from the point of view of green chemistry.

Diastereodivergent Intermolecular 1,2-Diamination of Unactivated Alkenes Enabled by Iodine Catalysis

The stereospecific, substrate (nitrogen source)-controlled intermolecular anti-and syn-1,2-diaminations of unactivated alkenes using the same catalysis (an iodine catalyst) is reported. The combined use of the two potential methods provides access to all of the disastereomeric forms of 1,2-diamines in spite of the availability of E-and Z-Alkenes, and the resulting products can be readily converted into free vicinal diamines.