65416-24-2Relevant articles and documents
Copper-catalyzed enantioselective carbenoid insertion into S-H bonds
Zhang, Yong-Zhen,Zhu, Shou-Fei,Cai, Yan,Mao, Hong-Xiang,Zhou, Qi-Lin
, p. 5362 - 5364 (2009)
An asymmetric carbenoid insertion into S-H bonds catalyzed by copper-chiral spiro bisoxazoline complexes has been developed, in which a series of α-mercaptoesters were produced in high yields with moderate to good enantioselectivities (up to 85% ee); this
Carboxylative Suzuki coupling reactions of benzyl chlorides with allyl pinacolborate catalyzed by palladium nanoparticles
Sun, Jian,Wang, Jiasheng,Feng, Xiujuan,Yamamoto, Yoshinori,Almansour, Abdulrahman I.,Arumugam, Natarajan,Kumar, Raju Suresh,Bao, Ming
, p. 1258 - 1262 (2018/06/21)
Palladium-catalyzed carboxylative Suzuki coupling reactions of benzyl chlorides with allyl pinacolborate were successfully conducted in the absence of any extra ligand to produce β,γ-unsaturated esters in satisfactory to good yields. The carboxylative Suzuki coupling reaction proceeded smoothly under mild conditions in the presence of palladium nanoparticles generated in situ through the formation of a π-benzylpalladium chloride intermediate.
Use of diethoxymethane as a solvent for phase-transfer esterification of carboxylic acids
Coleman, M. Todd
scheme or table, p. 1911 - 1913 (2012/06/04)
The esterification of carboxylic acids with selected primary alkyl halides in diethoxymethane (DEM) utilizing solid-liquid phase-transfer catalysis has been studied. The use of DEM as the solvent simplifies the process in that a single solvent can be used for both reaction and workup.
