6832-17-3

Basic information

• Product Name: Ethanone, 2-diazo-1-(4-methoxyphenyl)-
• CAS NO: 6832-17-3
• Molecular Formula: C9H8N2O2
• Molecular Weight: 176.175
• Mol File: 6832-17-3.mol
• Article Data: 30

Chemical Properties

• CAS DataBase Reference: Ethanone, 2-diazo-1-(4-methoxyphenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Ethanone, 2-diazo-1-(4-methoxyphenyl)-(6832-17-3)
• EPA Substance Registry System: Ethanone, 2-diazo-1-(4-methoxyphenyl)-(6832-17-3)

Safety Data

• Hazardous Substances Data: 6832-17-3(Hazardous Substances Data)

Upstream product

• 186581-53-3 diazomethane 
• 100-07-2 4-methoxy-benzoyl chloride 
• 23722-34-1 2-hydrazono-1-(4-methoxyphenyl)ethanone 
• 34933-41-0 sodium salt of p-methoxybenzoylacetaldehyde 
• 72818-30-5 Anisoyl-4-tolylsulfon 
• 31706-15-7 3-(4-methoxy-phenyl)-3-oxo-propionaldehyde 
• 100-09-4 4-methoxybenzoic acid 
• 100-06-1 1-(4-methoxyphenyl)ethanone 
• 38502-65-7 1-(4-nitrophenyl)-3-(4-methoxyphenyl)propane-1,3-dione 
• 6327-79-3 1-(4-methoxyphenyl)-3-phenylpropane-1,3-dione 
• 2632-13-5 2-Bromo-4'-methoxyacetophenone 
• 6595-28-4 2-azido-1-(4-methoxyphenyl)ethan-1-one 
• 18362-51-1 1,3-bis(4'-methoxyphenyl)propane-1,3-dione 
• 15191-68-1 4,4,4-trifluoro-1-(4-methoxyphenyl)-1,3-butanedione 

Downstream Products

• 21160-26-9 2-methoxy-1-(4-methoxy-phenyl)-ethanone 
• 23786-14-3 4-methoxy-phenyl acetic acid methyl ester 
• 33108-93-9 α-chloro-α-oximino-p-methoxyacetophenone 
• 20341-14-4 N-[2-(1,3-benzodioxol-5-yl)ethyl]-2-(4-methoxyphenyl)acetamide 
• 86601-72-1 2-benzylamino-1-(4-methoxy-phenyl)-ethanol 
• 58518-78-8 p-methoxyphenacyl acetate 
• 7397-16-2 (4-methoxy-phenyl)-glyoxal-bis-phenylhydrazone 
• 34800-47-0 2'-phenyl-(4-methoxyphenyl)acetohydrazide 
• 37818-09-0 1-(4-methoxy-phenyl)-2-((Z)-6-methyl-7,8-dihydro-6H-[1,3]dioxolo[4,5-g]isoquinolin-5-ylidene)-ethanone 
• 7714-03-6 1,1,2-Tris-methylmercapto-3-(4-methoxy-phenyl)-propanon-(3) 
• 7714-04-7 1,1,2-Tris-ethylmercapto-3-(4-methoxy-phenyl)-propanon-⁽³⁾ 
• 22177-09-9 (4-chloro-phenyl)-[5-(4-methoxy-phenyl)-6H-[1,3,4]thiadiazin-2-yl]-amine 
• 94960-18-6 N-[4-(4-methoxy-benzoyl)-[1,2,3]thiadiazol-5-yl]-3-methyl-benzamide 
• 93870-11-2 N-[4-(4-methoxy-benzoyl)-[1,2,3]thiadiazol-5-yl]-2-methyl-benzamide 

Relevant articles and documents

NovelN-transfer reagent for converting α-amino acid derivatives to α-diazo compounds

A novel universalN-transfer reagent for direct and effective transformation of α-amino ketones, acetamides, and esters to the corresponding α-diazo products under mild basic conditions has been developed. This one-step synthetic approach not only allows for generation of α-substituted-α-diazo carbonyl compounds from α-amino acid derivatives but also permits preparation of α-diazo dipeptides fromN-terminal dipeptides (32 examples, up to 91%).

Practical Application of the Aqueous 'Sulfonyl-Azide-Free' (SAFE) Diazo Transfer Protocol to Less α-C-H Acidic Ketones and Esters

The earlier described 'sulfonyl-Azide-free' ('SAFE') protocol for diazo transfer to CH-Acidic 1,3-dicarbonyl compounds (and their similarly activated congeners) has been extended to the less reactive monocarbonyl substrates, which previously required a se

Site-Selective Conversion of Azido Groups at Carbonyl α-Positions to Diazo Groups in Diazido and Triazido Compounds

This paper reports on the selective conversion of alkyl azido groups at the carbonyl α-position to diazo compounds. Through β-elimination of dinitrogen, followed by hydrazone formation/decomposition, α-azidocarbonyl moieties were transformed into α-diazo carbonyl groups in one step. As these reaction conditions do not involve aryl or general alkyl azides, site-selective conversions of di- and triazides were achieved. Through this method, the successive site-selective conjugation of the triazido molecule with three different components is demonstrated.