69161-61-1

Basic information

• Product Name: 2-(prop-2-en-1-yloxy)oxane
• CAS NO: 69161-61-1
• Molecular Weight: 142.198
• Mol File: 69161-61-1.mol
• Article Data: 64

Chemical Properties

• CAS DataBase Reference: 2-(prop-2-en-1-yloxy)oxane(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(prop-2-en-1-yloxy)oxane(69161-61-1)
• EPA Substance Registry System: 2-(prop-2-en-1-yloxy)oxane(69161-61-1)

Safety Data

• Hazardous Substances Data: 69161-61-1(Hazardous Substances Data)

Upstream product

• 110-87-2 3,4-dihydro-2H-pyran 
• 107-18-6 allyl alcohol 
• 33821-94-2 3-(tetrahydro-2H-pyran-2-yloxy)propyl bromide 
• 598-25-4 Dimethylallene 
• 917-54-4 methyllithium 
• 6089-04-9 3-(tetrahydropyran-2'-yloxy)propyne 
• 73746-50-6 2-allyloxy-3-bromotetrahydropyran 

Downstream Products

• 694-54-2 tetrahydro-2H-2-pyranol 
• 112471-51-9 2-(3-phenylpropoxy)tetrahydro-2H-pyran 
• 107-18-6 allyl alcohol 
• 13686-96-9 nonane-1,5-diol 
• 7310-51-2 oct-7-ene-1,5-diol 
• 4247-43-2 1-<(tetrahydropyran-2-yl)oxyl>-2-propanol 
• 69036-26-6 1-cyclohexyl-3-buten-1-ol 
• 2049-80-1 (2-propenyl)propanedioic acid diethyl ester 
• 3195-24-2 diallylmalonic acid diethyl ester 
• 13891-95-7 1-phenylhex-1,5-dien-3-ol 
• 80735-94-0 1-Phenyl-3-buten-1-ol 
• 275361-77-8 N-{2-[(Z)-3-(Tetrahydro-pyran-2-yloxy)-propenyl]-phenyl}-formamide 
• 113832-27-2 (Z)-2,6,6-Trimethyl-1-<3-(tetrahydro-2-pyranyloxy)-2-propen-1-yl>-2-cyclohexen-1-ol 
• 113832-35-2 (Z)-4-(Tetrahydro-2-pyranyloxy)-1-(2,6,6-trimethyl-1-cyclohexen-1-yl)-3-buten-1-ol 

Relevant articles and documents

Mild and efficient tetrahydropyranylation of alcohols-catalysis by lithium perchlorate in diethyl ether

Treatment of 3,4-dihydro-2H-pyran 1 with various alcohols 2 - 10 furnished the tetrahydropyranyl ethers 11 - 19 in the presence of 5M lithium perchlorate in diethyl ether (5M LPDE), which is essentially a neutral medium.

Selective Semi-Hydrogenation of Terminal Alkynes Promoted by Bimetallic Cu-Pd Nanoparticles

The selective semi-hydrogenation of terminal alkynes was efficiently performed, under mild reaction conditions (H 2 balloon, 110 °C), promoted by a bimetallic nanocatalyst composed of copper and palladium nanoparticles (5:1 weight ratio) supported on mesostructured silica (MCM-48). The Cu-PdNPS@MCM-48 catalyst, which demonstrated to be highly chemoselective towards the alkyne functionality, is readily prepared from commercial materials and can be recovered and reused after thermal treatment followed by reduction under H 2 atmosphere.

Room-Temperature Gold-Catalysed Arylation of Heteroarenes: Complementarity to Palladium Catalysis

Tailoring of the pre-catalyst, the oxidant and the arylsilane enables the first room-temperature, gold-catalysed, innate C?H arylation of heteroarenes. Regioselectivity is consistently high and, in some cases, distinct from that reported with palladium ca