7310-51-2Relevant articles and documents
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Bohlmann,F. et al.
, p. 1705 - 1706 (1964)
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A general electron transfer reduction of lactones using SmI 2-H2O
Szostak, Michal,Collins, Karl D.,Fazakerley, Neal J.,Spain, Malcolm,Procter, David J.
supporting information; experimental part, p. 5820 - 5824 (2012/08/28)
Herein we describe a strategy for the selective, electron transfer reduction of lactones of all ring sizes and topologies using SmI 2-H2O and a Lewis base to tune the redox properties of the complex. The current protocol permits instantaneous reduction of lactones to the corresponding diols in excellent yields, under mild reaction conditions and with useful chemoselectivity. We demonstrate the broad utility of this transformation through the reduction of complex lactones and sensitive drug-like molecules. Sequential electron transfer reactions and syntheses of deuterated diols are also described.
FeCl3-catalysed Zn-mediated allylation of cyclic enol ethers in water
Chakraborty,Roy
supporting information; experimental part, p. 509 - 512 (2012/08/07)
A mild and environment-friendly Zn-mediated allylation of dihydrofuran and dihydropyran catalysed by iron(III) chloride in water has been developed. [Figure not available: see fulltext.]
Tin mediated allylation reactions of enol ethers in water
Lin, Mei-Huey,Hung, Shiang-Fu,Lin, Long-Zhi,Tsai, Wen-Shing,Chuang, Tsung-Hsun
supporting information; experimental part, p. 332 - 335 (2011/03/23)
Under tin-mediated Barbier-type reaction conditions, hydration of enol ethers takes place to form aldehydes that undergo allylation reactions. By using this process, various homoallylic alcohols and 2-halohomoallylic alcohols are produced in good to excel