697-11-0Relevant articles and documents
Kinetic Studies of the Continuous Wave Laser-Induced Cyclization of Hexafluoro-1,3-butadiene
Zitter, R. N.,Koster, D. F.,Cheung, K.
, p. 1401 - 1402 (1985)
Kinetics of the isomerisation of hexafluoro-1,3-butadiene have been studied in the past by standard pyrolysis and by shock tubes, with conflicting results.The present study indicates that the pyrolysis results are correct and also indicates that vibrational-translational energy in hexafluoro-1,3-butadiene occurs through a vibrational mode that is nearly harmonic.
A T-shaped Ni[κ2-(CF2)4-] NHC complex: Unusual Csp3-F and M-CF bond functionalization reactions
Andrella, Nicholas O.,Sicard, Alexandre J.,Gorelsky, Serge I.,Korobkov, Ilia,Baker, R. Tom
, p. 6392 - 6397 (2015)
A T-shaped octafluoronickelacyclopentane-NHC complex is prepared and characterized. While the solid-state structure includes a weak isopropyl-CH3 agostic interaction, the reactivity of this complex with Lewis- and Bronsted acids is clearly enhanced by its low coordination number. Reaction with Me3SiOTf, for example, yielded a rare metal-heptafluorocyclobutyl complex whereas carboxylic acids gave substitution at the α-carbon and/or Ni-CF bond protonolysis to afford thermally robust 4H-octafluorobutyl Ni complexes.
MANUFACTURING METHOD OF PERFLUOROCYCLOALKENE COMPOUND
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Paragraph 0083-0091, (2020/05/14)
PROBLEM TO BE SOLVED: To obtain a perfluorocycloalkene compound high in conversion ratio of a reaction at high yield and high selectivity. SOLUTION: A perfluorocycloalkene compound represented by (1), where R1 to R4 are same or different, and represent a fluorine atom or a perfluoroalkadiene compound, is obtained by conducting a cyclization reaction of a perfluoroalkanediene compound represented by CR12=CR2-CR3=CR42, where R1 to R4 are same or different and represent a fluorine atom or a perfluoroalkyl group. The cyclization reaction can be conducted in presence of a catalyst, by a gas phase continuous flow type, or by the gas phase continuous flow type in presence of the catalyst. SELECTED DRAWING: None COPYRIGHT: (C)2020,JPOandINPIT
Preparation method of halogenation cycloolefin
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Paragraph 0070; 0071, (2019/08/20)
The invention relates to a preparation method of halogenation cycloolefin and belongs to the field of chemical synthesis. According to the preparation method, in an amide or alkylamine solvent, with halogenation cycloparaffin as a raw material, a dehalogenation reaction is conducted, and the target product halogenation cycloolefin is obtained. According to the method, the reaction conditions are mild, the yield of the halogenation cycloolefin is high, dangerous reduction agents such as metal or hydrogen do not need to be used, the technology is safe and reliable, solid waste such as metal halide is not generated, and a common distillation means can be used for effective industrial separation.