76573-34-7

Basic information

• Product Name: (-)-3-deoxy-1,2:4,5-di-O-isopropylidene-β-D-fructofuranos-3-yl benzoate
• Synonyms: (-)-3-deoxy-1,2:4,5-di-O-isopropylidene-β-D-fructofuranos-3-yl benzoate
• CAS NO: 76573-34-7
• Molecular Weight: 364.395
• Mol File: 76573-34-7.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: (-)-3-deoxy-1,2:4,5-di-O-isopropylidene-β-D-fructofuranos-3-yl benzoate(CAS DataBase Reference)
• NIST Chemistry Reference: (-)-3-deoxy-1,2:4,5-di-O-isopropylidene-β-D-fructofuranos-3-yl benzoate(76573-34-7)
• EPA Substance Registry System: (-)-3-deoxy-1,2:4,5-di-O-isopropylidene-β-D-fructofuranos-3-yl benzoate(76573-34-7)

Safety Data

• Hazardous Substances Data: 76573-34-7(Hazardous Substances Data)

Upstream product

• 25018-67-1 1,2;4,5-di-O-isopropylidene-β-D-(-)-fructopyranose 
• 98-88-4 benzoyl chloride 
• 7660-25-5 D-fructose 

Downstream Products

• 403500-67-4 C₆H₁₀O₄(C₃H₄)Si(CH₃)2C₄H₈OHNCOSO₂C₆H₄CH₂ 
• 403500-66-3 N-[(5S,8R,9R,10S)-10-(tert-Butyl-dimethyl-silanyloxy)-9-hydroxy-2,2-dimethyl-1,3,6-trioxa-spiro[4.5]dec-8-yl]-4-methyl-benzenesulfonamide 
• 403500-72-1 C₆H₁₀O₄(C₃H₄)Si(CH₃)2C₄H₈OHNCOCHC₆H₅ 
• 403500-73-2 C₆H₁₀O₄(C₃H₄)OHNCOCHC₆H₅ 
• 99648-50-7 3-O-benzoyl-4,5-dideoxy-1,2-O-isopropylidene-α-L-glycero-hex-4-en-2-ulopyranose 
• 697288-29-2 (2R,3R,4R,5R)-3,4-Dihydroxy-2,5-bis-hydroxymethyl-pyrrolidine-1-carbothioic acid phenylamide 
• 368452-21-5 5-azideo-3,4-di-O-benzoyl-5-deoxy-1,2-O-isopropylidene-β-L-sorbopyranose 
• 368452-03-3 3,4-di-O-benzoyl-5-deoxy-5-iodo-1,2-O-isopropylidene-β-L-sorbopyranose 
• 99648-59-6 3,4-di-O-benzoyl-1,2-O-isopropylidene-β-D-fructopyranose 
• 94801-02-2 5-azido-5-deoxy-D-fructopyranose 
• 59920-31-9 2,5-dideoxy-2,5-imino-D-mannitol 
• 99648-49-4 3-O-benzoyl-1,2-O-isopropylidene-β-D-fructopyranose 

Relevant articles and documents

Acyl chloride/DABCO-promoted acetal migration of 1,2:4,5-di-O-isopropylidene-d-fructopyranose

An unprecedented acetal migration was observed when 1,2:4,5-di-O-isopropylidene-d-fructose was treated with various acyl chlorides and 1,4-diaza-bicyclo[2.2.2]octane (DABCO). 2,3:4,5-Di-O-isopropylidene-d-fructose derivatives were isolated as the only pro

Electronic probing of ketone catalysts for asymmetric epoxidation. Search for more robust catalysts

Equation presented Ketones with a fused oxazolidinone were synthesized and investigated to determine the electronic effect of the substituents at α-positions of ketone catalysts on the Baeyer-Villiger oxidation and catalytic properties for asymmetric epoxidation. These new ketones give high yields and ee's with only 1 5 mol % catalyst. The current studies further show that the electronic effect is very important for the kitone-catalyzed epoxidation.