76689-65-1Relevant articles and documents
Thiadiazoles and Dihydrothiadiazoles. Part 5. Synthesis of 2,3-Dihydro-1,3,4-thiadiazoles by Reaction of Aldehydes or Ketones with Thioaroylhydrazines
Evans, D. Michael,Hill, Lawrence,Taylor, David R.,Myers, Malcolm
, p. 1499 - 1506 (2007/10/02)
A general method for the synthesis of 2,5- and 2,2,5-substituted 2,3-dihydro-1,3,4-thiadiazoles is described, involving the condensation of aldehydes or ketones with thioaroylhydrazines.Evidence for the cyclic nature of the products is discussed.The react
SEMICARBAZONES AND THIOSEMICARBAZONES OF THE HETEROCYCLIC SERIES. XLIV. CYCLIZATION OF ISATIN AND 1-ACETYLISATIN 3-THIOBENZOYLHYDRAZONES
Tomchin, A.B.
, p. 504 - 510 (2007/10/02)
Isatin 3-thiobenzoylhydrazone undergoes cyclization with the addition of the sulfur atom to the C3 atom and closure of the thiadiazole ring.In contrast, 3-thioaroylhydrazones of 1-acetylisatin undergo cyclization with participation of C2 and close the thiadiazine ring with the formation of derivatives of the new heterocyclic system thiadiazinoindole.