82128-66-3Relevant articles and documents
Multifunctional lanthanide-organic frameworks for fluorescent sensing, gas separation and catalysis
Liu, Xiaobin,Lin, Huan,Xiao, Zhenyu,Fan, Weidong,Huang, Ao,Wang, Rongming,Zhang, Liangliang,Sun, Daofeng
, p. 3743 - 3749 (2016)
Two lanthanide MOFs based on 3,3′-((2,3,6,7-tetramethoxyanthracene-9,10-diyl)bis(4,1-phenylene))diacrylic acid (H2LOMe), [Eu(LOMe)1.5(H2O)2]·3.5DMA·2H2O (1) and [Pr(LOMe/su
Porous GdIII-Organic Framework as a Dual-Functional Material for Cyanosilylation of Aldehydes and Ablation of Human Liver Cancer Cells
Han, Dong,Yan, Xiu-Li,Liu, Jian
, p. 422 - 427 (2019)
Metal-organic frameworks (MOFs) have gained great attention in recent years because they could behave as multifunctional materials which combine the advances of porous solids and coordination complexes. With the aim of constructing multifunctional MOFs, i
Application of an Electrochemical Microflow Reactor for Cyanosilylation: Machine Learning-Assisted Exploration of Suitable Reaction Conditions for Semi-Large-Scale Synthesis
Sato, Eisuke,Fujii, Mayu,Tanaka, Hiroki,Mitsudo, Koichi,Kondo, Masaru,Takizawa, Shinobu,Sasai, Hiroaki,Washio, Takeshi,Ishikawa, Kazunori,Suga, Seiji
supporting information, p. 16035 - 16044 (2021/09/02)
Cyanosilylation of carbonyl compounds provides protected cyanohydrins, which can be converted into many kinds of compounds such as amino alcohols, amides, esters, and carboxylic acids. In particular, the use of trimethylsilyl cyanide as the sole carbon source can avoid the need for more toxic inorganic cyanides. In this paper, we describe an electrochemically initiated cyanosilylation of carbonyl compounds and its application to a microflow reactor. Furthermore, to identify suitable reaction conditions, which reflect considerations beyond simply a high yield, we demonstrate machine learning-assisted optimization. Machine learning can be used to adjust the current and flow rate at the same time and identify the conditions needed to achieve the best productivity.
Multinuclear transition metal-containing polyoxometalates constructed from Nb/W mixed-addendum precursors: synthesis, structures and catalytic performance
Chen, Xuenian,Li, Na,Li, Shujun,Ma, Yubin,Xiao, Wanru,Zhang, Jie,Zhao, Yue
supporting information, p. 8690 - 8695 (2021/07/02)
Four new transition metal-containing Nb/W mixed-addendum POM trimers with the formula H19[M4(H2O)x(P2W15Nb3O62)3]·m(HCOOH)·nH2O (M = Cu,x= 15,m=
