82461-23-2

Basic information

• Product Name: 3-phenylhex-5-en-2-ol
• Synonyms: 3-phenylhex-5-en-2-ol
• CAS NO: 82461-23-2
• Molecular Weight: 176.258
• Mol File: 82461-23-2.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 3-phenylhex-5-en-2-ol(CAS DataBase Reference)
• NIST Chemistry Reference: 3-phenylhex-5-en-2-ol(82461-23-2)
• EPA Substance Registry System: 3-phenylhex-5-en-2-ol(82461-23-2)

Safety Data

• Hazardous Substances Data: 82461-23-2(Hazardous Substances Data)

Upstream product

• 130284-35-4 2-phenyl-pent-4-en-1-ol 
• 96-09-3 styrene oxide 
• 24401-36-3 2-phenyl-4-penten-1-al 
• 75-16-1 methylmagnesium bromide 
• 917-64-6 methyl magnesium iodide 

Downstream Products

• 132637-55-9 3-phenylhex-5-en-2-on p-tosylhydrazone 
• 132637-47-9 2-phenylhex-5-en-2-yl hydroperoxide 
• 89969-01-7 4-oxo-3-phenylpentanal 
• 26965-15-1 3-phenylhex-5-en-2-one 

Relevant articles and documents

Preparation of Unsaturated Hydroperoxides from N-Alkenyl-N'-p-tosylhydrazines

Unsaturated hydroperoxides (R1R2CHO2H), 2-phenylpent-4-enyl hydroperoxide (1), 3-phenylhex-5-en-2-yl hydroperoxide (2), 5-methylhex-5-en-2-yl hydroperoxide (3), cyclo-oct-4-enyl hydroperoxide (18), and cyclo-oct-3-enyl hydroperoxide (24) have each been prepared from the corresponding carbonyl compound (R1R2CO) by the sequence: i, conversion to the p-tosylhydrazone (R1R2C=N-NHTs); ii, reduction with sodium cyanoborohydride at pH 3.5 to give the N'-p-tosylhydrazine (R1R2CH-NH-NHTs); and iii, oxidation with hydrogen peroxide and sodium peroxide.Isomerisation occurs in the preparation of the cyclo-octenyl hydroperoxides, particuarly if the pH falls markedly below 3.5 in the reduction step.