82955-03-1

Basic information

• Product Name: 2-(4-(methylthio)phenyl)adamantan-2-ol
• CAS NO: 82955-03-1
• Molecular Weight: 274.427
• Mol File: 82955-03-1.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 2-(4-(methylthio)phenyl)adamantan-2-ol(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(4-(methylthio)phenyl)adamantan-2-ol(82955-03-1)
• EPA Substance Registry System: 2-(4-(methylthio)phenyl)adamantan-2-ol(82955-03-1)

Safety Data

• Hazardous Substances Data: 82955-03-1(Hazardous Substances Data)

Upstream product

• 700-58-3 2-Adamantanone 
• 18620-04-7 4-thioanisolemagnesium bromide 
• 3393-00-8 (4’-bromo-[1,1’-biphenyl]-4-yl)(methyl)sulfane 

Relevant articles and documents

Preparation of Functionalized Diaryl- and Diheteroaryllanthanum Reagents by Fast Halogen–Lanthanum Exchange

Aryl and heteroaryl halides (X=Br, I) undergo a fast and convenient halogen–lanthanum exchange with nBu2LaMe, which leads to functionalized diaryl- and diheteroaryllanthanum derivatives. Subsequent trapping reactions with selected electrophiles, such as ketones, aldehydes, or amides, proceeded smoothly at ?50 °C in THF, affording polyfunctionalized alcohols and carbonyl derivatives. Kinetic competition experiments revealed a similar reactivity trend as for Br/Mg exchange, but 106-times higher rates, making it comparable to Br/Li exchange.