84108-98-5Relevant articles and documents
Efficient visible-light photocatalytic aerobic oxidation of cyclic sulfamides to imines
Ming, Zong-Yao,Li, Kang-Rui,Meng, Fan-Jie,Shi, Lei,Jiang, Wen-Feng
supporting information, (2020/06/17)
A highly efficient photocatalytic aerobic oxidation of cyclic sulfamides to synthesize cyclic N-sulfonyl imines with Ir(ppy)2(dtbpy)PF6 as photocatalyst is reported. These environmentally friendly transformations exihibit good to excellent isolated yields and good generality with respect to both five-membered and six-membered cyclic sulfamides.
Sultam compound and preparation method thereof
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Paragraph 0054-0057; 0105-0107, (2019/11/12)
The invention provides a sultam compound and a preparation method thereof. The method provided by the invention specifically comprises the following steps: putting a catalyst C, sulfamide B and an oxidant D into an organic solvent, performing a reaction,
Vancomycin-iridium (III) interaction: An unexplored route for enantioselective imine reduction
Facchetti, Giorgio,Pellegrino, Sara,Bucci, Raffaella,Nava, Donatella,Gandolfi, Raffaella,Christodoulou, Michael S.,Rimoldi, Isabella
, (2019/08/07)
The chiral structure of antibiotic vancomycin (Van) was exploited as an innovative coordination sphere for the preparation of an IrCp* based hybrid catalysts. We found that Van is able to coordinate iridium (Ir(III)) and the complexation was demonstrated by several analytical techniques such as MALDI-TOF, UV, Circular dichroism (CD), Raman IR, and NMR. The hybrid system so obtained was employed in the Asymmetric Transfer Hydrogenation (ATH) of cyclic imines allowing to obtain a valuable 61% e.e. (R) in the asymmetric reduction of quinaldine 2. The catalytic system exhibited a saturation kinetics with a calculated efficiency of Kcat/KM = 0.688 h?1mM?1