86118-53-8

Basic information

• Product Name: (4-Methylphenyl)(c-2,t-3-diphenylcycloprop-r-1-yl)methanon
• Synonyms: (4-Methylphenyl)(c-2,t-3-diphenylcycloprop-r-1-yl)methanon
• CAS NO: 86118-53-8
• Molecular Weight: 312.411
• Mol File: 86118-53-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (4-Methylphenyl)(c-2,t-3-diphenylcycloprop-r-1-yl)methanon(CAS DataBase Reference)
• NIST Chemistry Reference: (4-Methylphenyl)(c-2,t-3-diphenylcycloprop-r-1-yl)methanon(86118-53-8)
• EPA Substance Registry System: (4-Methylphenyl)(c-2,t-3-diphenylcycloprop-r-1-yl)methanon(86118-53-8)

Safety Data

• Hazardous Substances Data: 86118-53-8(Hazardous Substances Data)

Upstream product

• 100-39-0 benzyl bromide 
• 41570-67-6 1-benzyltetrahydro-1H-thiophen-1-ium bromide 
• 4224-96-8 3-phenyl-1-p-tolylprop-2-en-1-one 
• 14182-15-1 S-benzyldimethylsulfonium bromide 
• 14802-30-3 (E)-1-(4-methylphenyl)-3-phenyl-2-propen-1-one 
• 1103-87-3 benzaldehyde triphenylphosphoranylidenehydrazone 

Relevant articles and documents

Generation of Diastereomeric Cyclopropanes from Benzylidenesulfuranes and Chalcones

The reaction of the benzylidenesulfuranes 2, available by deprotonation of the benzylsulfonium bromides 1, with chalcones 3, which are substituted in the aroyl part, leads to the stereoisomeric cyclopropanes 4 and 5.The stereochemistry of 4 and 5 is elucidated by spectroscopy.A carbenic mechanism of formation of 4 and 5 is excluded experimentally.