87248-70-2

Basic information

• Product Name: (2S,4S)-4-Methyl-2-phenyl-[1,3,2]dioxaphosphinane
• Synonyms: (2S,4S)-4-Methyl-2-phenyl-[1,3,2]dioxaphosphinane
• CAS NO: 87248-70-2
• Molecular Weight: 196.186
• Mol File: 87248-70-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (2S,4S)-4-Methyl-2-phenyl-[1,3,2]dioxaphosphinane(CAS DataBase Reference)
• NIST Chemistry Reference: (2S,4S)-4-Methyl-2-phenyl-[1,3,2]dioxaphosphinane(87248-70-2)
• EPA Substance Registry System: (2S,4S)-4-Methyl-2-phenyl-[1,3,2]dioxaphosphinane(87248-70-2)

Safety Data

• Hazardous Substances Data: 87248-70-2(Hazardous Substances Data)

Upstream product

• 24621-61-2 1,3-butanediol 
• 644-97-3 Dichlorophenylphosphine 

Downstream Products

• 87219-93-0 (R)-butyl methylphenylphosphine oxide 
• 1515-98-6 S(-)-benzyl methyl phenyl phosphine oxide 
• 721-74-4 R(+)-benzyl methyl phenyl phosphine oxide 
• 1515-99-7 (S)-(-)-Methylphenyl-n-propylphosphanoxid 
• 17170-48-8 (R)-(+)-methylphenyl-n-propylphosphine oxide 
• 26515-05-9 (-)-(S_P)-ethylmethylphenylphosphine oxide 
• 87219-86-1 (R)-Methyl-phenyl-phosphinic acid (S)-3-iodo-1-methyl-propyl ester 
• 87219-90-7 (R)-Allyl-phenyl-phosphinic acid (S)-3-bromo-1-methyl-propyl ester 
• 87219-88-3 (R)-Phenyl-propyl-phosphinic acid (S)-3-bromo-1-methyl-propyl ester 
• 87219-87-2 (R)-Ethyl-phenyl-phosphinic acid (S)-3-iodo-1-methyl-propyl ester 
• 87219-92-9 (S)-Phenyl-trityl-phosphinic acid (S)-3-chloro-1-methyl-propyl ester 
• 87219-89-4 (R)-Butyl-phenyl-phosphinic acid (S)-3-bromo-1-methyl-propyl ester 

Relevant articles and documents

PREPARATION OF OPTICALLY ACTIVE PHOSPHINE OXIDES BY REGIOSELECTIVE CLEAVAGE OF CYCLIC PHENYLPHOSPHONITE WITH ALKYL HALIDES

The Arbuzov reaction of (2S,4S)-methyl-2-phenyl-1,3,2-dioxaphosphorinane with various alkyl halides gave the diastereomerically pure phosphinates with regioselective cleavage of the primary carbon-oxygen bond.These phosphinates reacted with Grignard reage