87751-69-7

Basic information

• Product Name: (±)-trans-1,3-Diphenylallyl acetate
• Synonyms: (±)-trans-1,3-Diphenylallyl acetate;(+/-)-trans-1,3-Diphenylallyl acetate 97%;Acetic acid trans-1,3-diphenylallyl ester
• CAS NO: 87751-69-7
• Molecular Formula: C₁₇H₁₆O₂
• Molecular Weight: 252.30774
• Mol File: 87751-69-7.mol
• Article Data: 28

Chemical Properties

• Appearance: /
• BRN: 3610772
• CAS DataBase Reference: (±)-trans-1,3-Diphenylallyl acetate(CAS DataBase Reference)
• NIST Chemistry Reference: (±)-trans-1,3-Diphenylallyl acetate(87751-69-7)
• EPA Substance Registry System: (±)-trans-1,3-Diphenylallyl acetate(87751-69-7)

Safety Data

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26
• WGK Germany: 3
• Hazardous Substances Data: 87751-69-7(Hazardous Substances Data)

Usage

Description

(±)-trans-1,3-Diphenylallyl acetate is a chiral chemical compound with the molecular formula C18H16O2. It belongs to the class of allyl acetates, characterized by a double bond between carbon atoms. (±)-trans-1,3-Diphenylallyl acetate is known for its unique structure and reactivity, making it a versatile building block in the synthesis of various organic compounds, including pharmaceuticals, fragrances, and specialty chemicals. Its dual mirror-image forms add to its complexity and applicability in different fields.

Uses

Used in Organic Synthesis:
(±)-trans-1,3-Diphenylallyl acetate is utilized as a key starting material in organic synthesis for the production of a wide range of organic compounds. Its reactivity and structural features make it a valuable component in creating pharmaceuticals, fragrances, and specialty chemicals.
Used in Pharmaceutical Industry:
In the pharmaceutical sector, (±)-trans-1,3-Diphenylallyl acetate serves as an essential intermediate in the synthesis of various drugs. Its unique properties allow for the development of new medicinal compounds with potential therapeutic applications.
Used in Fragrance Industry:
(±)-trans-1,3-Diphenylallyl acetate is employed as a building block for creating unique fragrances and scents. Its chemical structure contributes to the development of novel aroma compounds used in perfumes, cosmetics, and other scented products.
Used in Food and Beverage Industry:
As a flavoring agent and aroma compound, (±)-trans-1,3-Diphenylallyl acetate plays a significant role in enhancing the taste and smell of various food and beverage products. Its incorporation into these products contributes to their overall sensory appeal.
Used in Scientific Research:
(±)-trans-1,3-Diphenylallyl acetate is also an important compound in scientific research, where it is studied for its properties and potential applications in various chemical and biological processes. Researchers explore its reactivity and behavior in different reaction conditions to gain insights into its potential uses and mechanisms.

Upstream product

• 14371-10-9 (E)-3-phenylpropenal 
• 108-24-7 acetic anhydride 
• 100-58-3 phenylmagnesium bromide 
• 62668-02-4 (E)-1,3-diphenyl-2-propen-1-ol 
• 108-22-5 Isopropenyl acetate 
• 75-36-5 acetyl chloride 
• 4663-33-6 1,3-diphenyl-3-hydroxypropene 
• 108-86-1 bromobenzene 
• 614-47-1 1,3-diphenyl-propen-3-one 
• 104-55-2 3-phenyl-propenal 
• 64847-78-5 (E)-1,1-diacetoxy-3-phenylprop-2-ene 
• 591-50-4 iodobenzene 
• 7217-71-2 1-phenyl-2-propenyl acetate 
• 98-80-6 phenylboronic acid 

Downstream Products

• 136859-93-3 (S)-1',1'-dimethylethyl 2-carbo-1'',1''-dimethylethoxy-3,5-diphenylpent-4-enoate 
• 136859-93-3 (R)-1',1'-dimethylethyl 2-carbo-1'',1''-dimethylethoxy-3,5-diphenylpent-4-enoate 
• 136859-90-0 2-Benzyl-2-((E)-1,3-diphenyl-allyl)-malonic acid dimethyl ester 
• 95071-02-6 (R)-methyl 2-carbomethoxy-3,5-diphenylpent-4-enoate 
• 177468-91-6 (E)-dimethyl (1,3-diphenylprop-2-en-1-yl)propanedioate 
• 95071-02-6 dimethyl 2-[(E)-(S)-1,3-diphenylallyl]-malonate 
• 18916-14-8 trans-prop-2-ene-1,1,3-triyltribenzene 
• 130866-13-6 (E)-2-(Diethoxy-phosphoryl)-3,5-diphenyl-pent-4-enoic acid ethyl ester 
• 136859-91-1 2-((E)-(R)-1,3-Diphenyl-allyl)-2-(2,2,2-trifluoro-acetylamino)-malonic acid dimethyl ester 
• 136859-91-1 2-((E)-(S)-1,3-Diphenyl-allyl)-2-(2,2,2-trifluoro-acetylamino)-malonic acid dimethyl ester 
• 204578-86-9 ((1E,5E)-hexa-1,5-diene-1,3,4,6-tetrayl)tetrabenzene 
• 3412-44-0 (1E)-1,3-diphenylpropene 
• 121440-78-6 (E)-N-(1,3-diphenyl-1λ³-allyl)-4-methylbenzenesulfonamide 
• 119477-58-6 (E)-(S)-2-Acetyl-3,5-diphenyl-pent-4-enoic acid methyl ester 

Relevant articles and documents

Pd-Catalyzed Nazarov-Type Cyclization: Application in the Total Synthesis of β-Diasarone and Other Complex Cyclopentanoids

We describe the palladium-catalyzed Nazarov-type cyclization of easily accessible (hetero)arylallyl acetates to pentannulated (hetero)arenes. This method provides ready access to various types of bi-, tri-, tetra-, and pentacyclic cyclopentanoids under ne

Carbamate-based P,O-ligands for asymmetric allylic alkylations

Herein we report the design and successful catalytic application of modified Trost-ligands in asymmetric allylic alkylation (AAA) reactions. A small set of carbamate-monophosphine P,O-ligands has been prepared in a straightforward two-step synthetic procedure. After optimization of the reaction conditions, high catalytic activities and excellent enantioselectivity up to >99% have been attained.

Synthetic and mechanistic studies in enantioselective allylic substitutions catalysed by palladium complexes of a modular class of axially chiral quinazoline-containing ligands

The application of palladium complexes of a modular series of axially chiral phosphinamine ligands, the Quinazolinaps, to the enantioselective alkylation of 1,3-diphenyl-2-propenyl acetate with dimethyl malonate and methyl dimethyl malonate is described.