3412-44-0Relevant articles and documents
Shapiro
, p. 345 (1968)
Nickel-Catalyzed C-Br/C-H Bis-phenylation of Methyl 4-Bromocrotonate: A Stereoselective Entry to Methyl (E)-3,4-Diphenylbut-2-enoate
Funicello, Maria,Chiummiento, Lucia,Lupattelli, Paolo,Tramutola, Francesco
, p. 1799 - 1806 (2015)
A method for C-Br/C-H bis-phenylation of methyl 4-bromocrotonate via nickel-catalyzed cross-coupling reaction has been developed. This protocol involves commercially available catalyst components and furnishes a suitable doubly phenylated building block.
Vinylation of Benzylic Amines via C-N Bond Functionalization of Benzylic Pyridinium Salts
Guan, Weiye,Liao, Jennie,Watson, Mary P.
, p. 3231 - 3237 (2018)
Cross-couplings of benzylic pyridinium salts and vinylboronic acids or esters have been developed. Via benzylic pyridinium intermediates, benzylic amines can be engaged in these cross-couplings through C-N bond functionalization. This method boasts mild reaction conditions and excellent tolerance for heteroaryl substituents and a range of functional groups.
Palladacycle-Catalyzed Regioselective Heck Reaction Using Diaryliodonium Triflates and Aryl Iodides
Hou, Cheng,Lei, Lu,Liang, Cui,Mo, Dong-Liang,Wang, Zhi-Xin,Zou, Pei-Sen
supporting information, p. 663 - 667 (2022/01/28)
We describe a P-containing palladacycle-catalyzed regioselective Heck reaction of 2,3-dihydrofuran with diaryliodonium salts and aryl iodides to afford 2-aryl-2,5-dihydrofurans and 2-aryl-2,3-dihydrofurans, respectively, in good yields. Mechanistic studie
Pd-Catalyzed Nazarov-Type Cyclization: Application in the Total Synthesis of β-Diasarone and Other Complex Cyclopentanoids
Bankar, Siddheshwar K.,Ramasastry, S. S. V.,Singh, Bara
supporting information, (2022/02/05)
We describe the palladium-catalyzed Nazarov-type cyclization of easily accessible (hetero)arylallyl acetates to pentannulated (hetero)arenes. This method provides ready access to various types of bi-, tri-, tetra-, and pentacyclic cyclopentanoids under ne