900519-21-3

Basic information

• Product Name: ((E)-(S)-1-(2-Benzyloxy-ethyl)-7-{2-[3-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-propyl]-[1,3]dithian-2-yl}-4-methyl-hept-4-enyloxy)-tert-butyl-dimethyl-silane
• Synonyms: ((E)-(S)-1-(2-Benzyloxy-ethyl)-7-{2-[3-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-propyl]-[1,3]dithian-2-yl}-4-methyl-hept-4-enyloxy)-tert-butyl-dimethyl-silane
• CAS NO: 900519-21-3
• Molecular Weight: 637.077
• Mol File: 900519-21-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: ((E)-(S)-1-(2-Benzyloxy-ethyl)-7-{2-[3-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-propyl]-[1,3]dithian-2-yl}-4-methyl-hept-4-enyloxy)-tert-butyl-dimethyl-silane(CAS DataBase Reference)
• NIST Chemistry Reference: ((E)-(S)-1-(2-Benzyloxy-ethyl)-7-{2-[3-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-propyl]-[1,3]dithian-2-yl}-4-methyl-hept-4-enyloxy)-tert-butyl-dimethyl-silane(900519-21-3)
• EPA Substance Registry System: ((E)-(S)-1-(2-Benzyloxy-ethyl)-7-{2-[3-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-propyl]-[1,3]dithian-2-yl}-4-methyl-hept-4-enyloxy)-tert-butyl-dimethyl-silane(900519-21-3)

Safety Data

• Hazardous Substances Data: 900519-21-3(Hazardous Substances Data)

Upstream product

• 900519-18-8 [(E)-(S)-1-(2-Benzyloxy-ethyl)-7-iodo-4-methyl-hept-4-enyloxy]-tert-butyl-dimethyl-silane 
• 900519-20-2 (R)-4-(3-[1,3]Dithian-2-yl-propyl)-2,2-dimethyl-[1,3]dioxolane 
• 900519-17-7 2,2-Dimethyl-propionic acid (E)-(S)-9-benzyloxy-7-(tert-butyl-dimethyl-silanyloxy)-4-methyl-non-3-enyl ester 
• 91285-62-0 (S)-1-(benzyloxy)-3-hydroxyhex-5-ene 
• 133494-69-6 (R)-4-but-3-enyl-2,2-dimethyl[1,3]dioxolane 
• 115114-87-9 (2R)-2-(2-benzyloxyethyl)oxirane 
• 365404-30-4 [3-benzyloxy-1-(2-iodo-ethyl)-propoxy]-tert-butyl-dimethyl-silane 
• 365404-49-5 (S)-5-(benzyloxy)-3-(tert-butyldimethylsilyloxy)pentan-1-ol 
• 251998-89-7 (R)-5-iodo-1,2-O-isopropylidenepentane-1,2-diol 
• 133008-08-9 (4R)-3-(2,2-dimethyl-1,3-dioxolan-4-yl)propan-1-ol 
• 236427-78-4 (S)-((1-(benzyloxy)hex-5-en-3-yl)oxy)(tert-butyl)dimethylsilane 

Downstream Products

• 900519-23-5 (E)-(S)-13-Benzyloxy-11-(tert-butyl-dimethyl-silanyloxy)-1-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-8-methyl-tridec-7-en-4-ol 
• 900519-22-4 (E)-(S)-13-Benzyloxy-11-(tert-butyl-dimethyl-silanyloxy)-1-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-8-methyl-tridec-7-en-4-one 

Relevant articles and documents

Unified total synthesis of pteriatoxins and their diastereomers

A unified total synthesis is reported to access all of the possible diastereomers of pteriatoxins A-C, with the use of an intramolecular Diels-Alder reaction as the key step to form the carbo-macrocyclic core structure. The C34/C35-diol protecting groups were found to have significant effects on both the exo/endo-selectivity and the exo-facial selectivity of the intramolecular Diels-Alder process. Copyright