90365-18-7

Basic information

• Product Name: Benzenepropanoyl chloride, a-[[(4-methylphenyl)sulfonyl]amino]-
• CAS NO: 90365-18-7
• Molecular Formula: C16H16ClNO3S
• Molecular Weight: 337.827
• Mol File: 90365-18-7.mol
• Article Data: 17

Chemical Properties

• CAS DataBase Reference: Benzenepropanoyl chloride, a-[[(4-methylphenyl)sulfonyl]amino]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenepropanoyl chloride, a-[[(4-methylphenyl)sulfonyl]amino]-(90365-18-7)
• EPA Substance Registry System: Benzenepropanoyl chloride, a-[[(4-methylphenyl)sulfonyl]amino]-(90365-18-7)

Safety Data

• Hazardous Substances Data: 90365-18-7(Hazardous Substances Data)

Upstream product

• 98-59-9 p-toluenesulfonyl chloride 
• 13505-32-3 N-tosyl-(S)-phenylalanine 
• 150-30-1 Phenylalanine 
• 34635-34-2 N-tosylphenylalanine 
• 63-91-2 L-phenylalanine 

Downstream Products

• 120402-85-9 N-tosyl-L-phenylalanyl-4-methylcoumaryl-7-amide 
• 1197023-71-4 (S)-N-(tosyl)phenylalaninyl-(S)-O-methyl-α-methylisoserine methyl ester 
• 1197023-72-5 (S)-N-(tosyl)phenylalaninyl-(S)-α-methylisoserine methyl ester 
• 1438047-52-9 C₂₄H₂₆N₂O₃S 
• 1438047-66-5 C₁₉H₂₄N₂O₃S 
• 1438047-79-0 C₂₈H₂₈N₂O₃S 
• 206441-84-1 3-tert-butoxycarbonylamino-2-methyl-6-[3-phenyl-2-(toluene-4-sulfonylamino)-propionylamino]-benzoic acid 2-trimethylsilanyl-ethyl ester 

Relevant articles and documents

Sulfonamide phenylalanine (SPA) series of analogues as an antibacterial, antifungal, anticancer agents along with p53 tumor suppressor-DNA complex inhibitor–part 1

A series of N-[1-benzyl-2-oxo-2-substituted(ethyl)] benzene/p-toluene sulfonamide (K1–K12) are synthesized. Structure of the synthesized analogues has been confirmed by FT-IR, 1H & 13C NMR and ESI-MS spectroscopic techniques. All the

Metal-Free N–H/C–H Coupling for Efficient Asymmetric Synthesis of Chiral Dihydroquinoxalinones from Readily Available α-Amino Acids

We have developed a method for the synthesis of dihydroquinoxalinones via intramolecular N–H/C–H coupling using hypervalent iodine. The starting materials were prepared from inexpensive and readily available aniline and amino acid derivatives. Various functional groups were tolerated to give multisubstituted dihydroquinoxalinones in moderate to excellent yields. The chirality of the amino acid was transferred to the desired target compound without a loss of enantiomeric excess. Preliminary mechanistic studies indicated that the reaction proceeds via an ionic mechanism.

Synthetically amenable amide derivatives of tosylated-amino acids as organocatalysts for enantioselective allylation of aldehydes: Computational rationale for enantioselectivity

A phenylalanine derived chiral amide is developed that serves as an effective organocatalyst for the reaction of allyltrichlorosilane with aryl, hetero-aryl and α,β-unsaturated aldehydes to afford the desired homoallylic alcohols in good yield (up to 90%)