926885-10-1Relevant articles and documents
Stereoselective tricarbonylchromium migration reactions in axially chiral biaryl chromium complexes
Kamikawa, Ken,Nishino, Kouta,Sakamoto, Tomohiro,Kinoshita, Shunsuke,Matsuzaka, Hiroyuki,Uemura, Motokazu
, p. 678 - 684 (2008/02/06)
The tricarbonylchromium group in thermodynamically unstable biaryl chromium complexes with a coordinating heteroatom at the side chain stereoselectively migrated to the other arene face to release the steric repulsion.