929721-54-0Relevant articles and documents
Asymmetric sulfur-ylide-mediated formal [4+1]-annulation reaction: Scope and mechanism
Clergue, Sébastien,Rousseau, Olivier,Delaunay, Thierry,Dequirez, Geoffroy,Tran, Trieu-Van,Aakchioui, Soumia El,Barozzino-Consiglio, Gabriella,Robiette, Rapha?l
, p. 11417 - 11425 (2018/10/21)
A formal [4+1]-annulation strategy between sulfur ylides and 1,3-dienes was developed to afford functionalized cyclopentanoids. The process consists of a stereoselective cyclopropanation reaction followed, in situ, by a stereospecific MgI2-cata
Synthesis and characterization of new chiral palladium β-diimine complexes
Domin, Doris,Benito-Garagorri, David,Mereiter, Kurt,Hametner, Christian,Fr?hlich, Johannes,Kirchner, Karl
, p. 1048 - 1057 (2007/10/03)
The synthesis and characterization of a range of chiral β-diimine ligands and their complexes with palladium(II) has been investigated. The introduction of chirality can be easily achieved through a combination of both achiral and chiral building blocks.