1,3-Dihydroxymethyl-4,5-dihydroxyimidazol-2-one supplier

Name
4,5-dihydroxy-1,3-bis(hydroxymethyl)imidazolidin-2-one
EINECS 217-451-6
CAS No. 1854-26-8
Article Data1
CAS DataBase
Density 1.5628 (rough estimate)
Solubility
Melting Point
Formula C5H10 N2 O5
Boiling Point 621.4°C at 760 mmHg
Molecular Weight 178.145
Flash Point 329.6°C
Transport Information
Appearance
Safety An eye and severe skin irritant. Mutation data reported. When heated to decomposition it emits toxic fumes of NO_x.
Risk Codes
Molecular Structure
Hazard Symbols
Synonyms 1,3-Bis(hydroxymethyl)-4,5-dihydroxy-2-imidazolidinone;1,3-Bis(hydroxymethyl)-4,5-dihydroxy-2-imidazolidone;1,3-Bis(hydroxymethyl)-4,5-dihydroxyimidazolidone;1,3-Di(hydroxymethyl)-4,5-dihydroxy-2-imidazolidinone;1,3-Dimethylol-4,5-dihydroxy-2-imidazolidinone;1,3-Dimethylol-4,5-dihydroxy-2-imidazolidone;1,3-Dimethylol-4,5-dihydroxyethyleneurea; 1,3-Dimethylol-4,5-dihydroxyimidazolidone;2D; 4,5-Dihydroxy-1,3-bis(hydroxymethyl)imidazolidin-2-one;4,5-Dihydroxy-1,3-dimethylol-2-imidazolidinone;4,5-Dihydroxy-1,3-dimethylolethyleneurea;4,5-Dihydroxy-2-oxo-1,3-dimethylolimidazolidine; 4,5-Dihydroxy-N,N'-dimethylolethyleneurea;Aerotex 900; Ahuramine YX; Arkofix NDF; Arkofix NG; Beckamine NS 11;Bis(hydroxymethyl)dihydroxyethyleneurea; Carbamol GL; Cassurit LR; DMDHEU;Depremol G; Dihydroxydimethylolethyleneurea; Dihydroxyethylenedimethylolurea;Dimethyloldihydroxyethyleneurea; Dimethyloldihydroxyimidazolidinone;Dimethylolglyoxalmonoureine; Dimethylolglyoxalurea; Durex GL 300; Finish KVS;Finish KVSI; Firmatex RK; Fixapret CP; Fixapret CP 40; Fixapret CPA; FixapretCPK; Fixapret CPN; Fixapret CPNS; Fixapret TX 2386; Freeaz 900; Freerez 845;Freerez 900; Freerez 980; G 1; Hylite LF; Intex 510; Karbamol GL; KnittexEverfit LE; Knittex LE; N,N'-Bis(hydroxymethyl)-4,5-dihydroxyethyleneurea;N,N'-Dimethylol-4,5-dihydroxyethyleneurea; N,N'-Dimethyloldihydroxyethyleneurea;N,N'-dimethylol-4,5-dihydroxy-2-imidazolidinone; Neuperm GFK; Neuperm GFN;PatCoRez P 53; Permafresh 113B; Permafresh 182; Permafresh 183; Permafresh LF;Permafresh LF 2; Permafresh LH; Permafresh LKS; Protocol C; Protocol CM; ProxDW; React HE; Reactant 2035; Reactant DH; Reapret KPN; Sarcoset GM; SumitexFSK; Sumitex NS 19; Sumitex NS 1Spe; Sumitex NS 2; Sumitex NS 200; SumitexResin NS 19; Valrez 248; Verapret DH; Verapret DKh; WNM
PSA 104.47000
LogP -2.86380

Synthetic route

: 3720-97-6
4,5-dihydroxy-2-imidazolidinone

: 50-00-0
formaldehyd

: 1854-26-8
dimethyloldihydroxyethylene urea

Conditions

Conditions	Yield
With disodium hydrogenphosphate; sodium dihydrogenphosphate; 2-(N,N-dimethylamino)ethanol at 50℃; for 4h; Reagent/catalyst; Temperature;

1,3-Dihydroxymethyl-4,5-dihydroxyimidazol-2-one Chemical Properties

Empirical Formula: C₅H₁₀N₂O₅
Molecular Weight: 178.1433
EINECS: 217-451-6
Index of Refraction: 1.669
Density: 1.809 g/cm³
Flash Point: 232.3 °C
Enthalpy of Vaporization: 83.17 kJ/mol
Boiling Point: 460.4 °C at 760 mmHg
Vapour Pressure: 2.06E-10 mmHg at 25 °C
Solubility: Water soluble
Appearance: Clear pale yellow 40% aqueous solution
Product Categories: Textile finishing agents;Textile dyeing and finishing auxiliaries;Chemical additives
Structure of Dimethyloldihydroxyethyleneurea (CAS NO.1854-26-8):

IUPAC Name of Dimethyloldihydroxyethyleneurea (CAS NO.1854-26-8): 4,5-Dihydroxy-1,3-bis(hydroxymethyl)imidazolidin-2-one

1,3-Dihydroxymethyl-4,5-dihydroxyimidazol-2-one Uses

Dimethyloldihydroxyethyleneurea (CAS NO.1854-26-8) is used as shaping durable fabric finishing agent, having good storage stability, fine properties of washing and hydrolysis. And it is suitable for fabric finishing colors. It is mainly used for polyester / cotton blended fabric finishing and has good keeping of its elasticity.

1,3-Dihydroxymethyl-4,5-dihydroxyimidazol-2-one Production

First, take 490 kg of Glyoxal (100% total) into the reactor,keep stirring and adding 20% to 25% Na₂CO₃ aqueous solution. Adjust pH value to 5 ~ 5.5. Adding Urea , and stirring for being dissolved, and then gradually warming to about 35 °C, then let automatic temperature to 45 °C for the reaction 1 h, then keeping it at 50 °C for 3 h, at last cooling it to 40 °C for backup. Scecond, adding 37% of the 1 350 kg of Formaldehyde in aqueous solution into the above-mentioned compounds, and using 20% Na₂CO₃ to adjust the pH value to 8 ~ 8.5. At 50 °C having insulation 3 h, and then being cooled to room temperature. Using acid for adjusting to 6 to 6.5. Now, you will get the product: Dimethyloldihydroxyethyleneurea (CAS NO.1854-26-8).

1,3-Dihydroxymethyl-4,5-dihydroxyimidazol-2-one Toxicity Data With Reference

1.	skn-rbt 500 mg/24H SEV	28ZPAK Sbornik Vysledku Toxixologickeho Vysetreni Latek A Pripravku Marhold, J.V.,Institut Pro Vychovu Vedoucicn Pracovniku Chemickeho Prumyclu Praha,Czechoslovakia.: 1972,269.
2.	eye-rbt 500 mg/24H MLD	28ZPAK Sbornik Vysledku Toxixologickeho Vysetreni Latek A Pripravku Marhold, J.V.,Institut Pro Vychovu Vedoucicn Pracovniku Chemickeho Prumyclu Praha,Czechoslovakia.: 1972,269.
3.	mmo-sat 3333 µg/plate	ENMUDM Environmental Mutagenesis. 9 (Suppl 9)(1987),1.
4.	slt-dmg-orl 60 ppb	EMMUEG Environmental and Molecular Mutagenesis. 23 (1994),51.

1,3-Dihydroxymethyl-4,5-dihydroxyimidazol-2-one Consensus Reports

Reported in EPA TSCA Inventory.

1,3-Dihydroxymethyl-4,5-dihydroxyimidazol-2-one Safety Profile

An eye and severe skin irritant. Mutation data reported. When heated to decomposition it emits toxic fumes of NO_x.

1,3-Dihydroxymethyl-4,5-dihydroxyimidazol-2-one Specification

Dimethyloldihydroxyethyleneurea ,its cas register number is 1854-26-8. It also can be called 4,5-Dihydroxy-1,3-bis(hydroxymethyl)-2-imidazolidinone ; and 2-Imidazolidinone, 4,5-dihydroxy-1,3-bis(hydroxymethyl)- .

Product Name

4,5-dihydroxy-1,3-bis(hydroxymethyl)imidazolidin-2-one