4,4'-Bis(methoxymethyl)-1,1'-biphenyl supplier

Name
4,4'-Bis(methoxymethyl)-1,1'-biphenyl
EINECS
CAS No. 3753-18-2
Article Data6
CAS DataBase
Density 1.039 g/cm³
Solubility
Melting Point 49-50 °C
Formula C₁₆H₁₈O₂
Boiling Point 337.3 °C at 760 mmHg
Molecular Weight 242.318
Flash Point 125.4 °C
Transport Information
Appearance
Safety
Risk Codes R36/37/38
Molecular Structure
Hazard Symbols Xi
Synonyms p,p'-Bitolyl,a,a'-dimethoxy- (7CI,8CI);4,4'-Bis(methoxymethyl)biphenyl;
PSA 18.46000
LogP 3.64640

Synthetic route

: 92-52-4
biphenyl

: 109-87-5
Dimethoxymethane

A: 86130-05-4
4-(methoxymethyl)-1,1'-biphenyl

B: 3753-18-2
4,4′-bis(methoxymethyl)biphenyl

Conditions

Conditions	Yield
mordenite SiO2/Al2O3 90 In cyclohexane at 120℃; for 4h; Product distribution / selectivity;

...Expand

: 1195-44-4
4-chlorobenzyl methyl ether

: 3753-18-2
4,4′-bis(methoxymethyl)biphenyl

Conditions

Conditions	Yield
With zinc; 5-trimethylsilyl-2,2'-bipyridine; nickel dibromide In 1-methyl-pyrrolidin-2-one at 20 - 70℃; Inert atmosphere;
With zinc; nickel dibromide; 5,5’-bis(trimethylsilyl)-2,2’-bipyridine In 1-methyl-pyrrolidin-2-one at 20 - 70℃; Inert atmosphere;

: diethyl 2-(cycloheptene-1-yl)-cyclobuten-1-yl phosphate

: 4-(methoxymethyl)phenylzinc chloride lithium chloride

A: 3753-18-2
4,4′-bis(methoxymethyl)biphenyl

B: 1-cycloheptenyl-2-[4-(methoxymethyl)phenyl]cyclobutene

Conditions

Conditions	Yield
With aluminum (III) chloride; C36H28Cl2OP2Pd In tetrahydrofuran at 50℃; for 17h; Negishi Coupling; Overall yield = 73 %; Overall yield = 0.451 g;

...Expand

: 3753-18-2
4,4′-bis(methoxymethyl)biphenyl

: 66-98-8
4,4'-diformylbiphenyl

Conditions

Conditions	Yield
With sodium bromate; acetic acid at 90℃; for 1.5h; Product distribution / selectivity;	93.3 %Chromat.

4,4'-Bis(methoxymethyl)-1,1'-biphenyl Specification

The 1,1'-Biphenyl,4,4'-bis(methoxymethyl)- is an organic compound with the formula C₁₆H₁₈O₂. The IUPAC name of this chemical is 1-(methoxymethyl)-4-[4-(methoxymethyl)phenyl]benzene. With the CAS registry number 3753-18-2, it is also named as 4,4-Bis-(methoxy-mehtyl) biphenyl. The product's categories are Biphenyl Derivatives; Biphenyl & Diphenyl ether. Besides, it should be stored in a dark closed and dry place. It is used for synthesis of flame-retardant resins, in particular for synthesis of liquid crystal polymer and synthesis of polymer resin.

Physical properties about 1,1'-Biphenyl,4,4'-bis(methoxymethyl)- are: (1)ACD/LogP: 3.45; (2)ACD/LogD (pH 5.5): 3.45; (3)ACD/LogD (pH 7.4): 3.45; (4)ACD/BCF (pH 5.5): 248.17; (5)ACD/BCF (pH 7.4): 248.17; (6)ACD/KOC (pH 5.5): 1802.04; (7)ACD/KOC (pH 7.4): 1802.04; (8)#H bond acceptors: 2; (9)#Freely Rotating Bonds: 5; (10)Polar Surface Area: 18.46 Å²; (11)Index of Refraction: 1.542; (12)Molar Refractivity: 73.43 cm³; (13)Molar Volume: 233 cm³; (14)Polarizability: 29.11×10^-24cm³; (15)Surface Tension: 36.5 dyne/cm; (16)Density: 1.039 g/cm³; (17)Flash Point: 125.4 °C; (18)Enthalpy of Vaporization: 55.75 kJ/mol; (19)Boiling Point: 337.3 °C at 760 mmHg; (20)Vapour Pressure: 0.000208 mmHg at 25°C.

You can still convert the following datas into molecular structure:
(1)SMILES: O(C)Cc1ccc(cc1)c2ccc(cc2)COC
(2)InChI: InChI=1/C16H18O2/c1-17-11-13-3-7-15(8-4-13)16-9-5-14(6-10-16)12-18-2/h3-10H,11-12H2,1-2H3
(3)InChIKey: MODAACUAXYPNJH-UHFFFAOYAT
(4)Std. InChI: InChI=1S/C16H18O2/c1-17-11-13-3-7-15(8-4-13)16-9-5-14(6-10-16)12-18-2/h3-10H,11-12H2,1-2H3
(5)Std. InChIKey: MODAACUAXYPNJH-UHFFFAOYSA-N

Product Name

4,4'-Bis(methoxymethyl)-1,1'-biphenyl

Synthetic route

4,4'-Bis(methoxymethyl)-1,1'-biphenyl Specification

Related Products

Hot Products