Ammonium perfluorooctanoate supplier

Name
PERFLUOROOCTANOIC ACID AMMONIUM SALT
EINECS 223-320-4
CAS No. 3825-26-1
Article Data1
CAS DataBase
Density 1.745g/cm³
Solubility
Melting Point 163-165(dec.)
Formula C8H F15 O2 . H3 N
Boiling Point 188°Cat760mmHg
Molecular Weight 431.101
Flash Point 62.1°C
Transport Information
Appearance
Safety Confirmed carcinogen. Poison by inhalation. Moderately toxic by ingestion. An eye and skin irritant. Experimental reproductive effects. When heated to decomposition it emits toxic fumes of F⁻ and NH₃.
Risk Codes R22;R36/38;
Molecular Structure
Hazard Symbols Toxic by inhalation and skin contact. TLV: 0.01 mg/m³.
Synonyms Octanoicacid, pentadecafluoro-, ammonium salt (8CI,9CI);Ammonium pentadecafluorooctanoate;Ammonium perfluorocaprylate;Ammonium perfluorooctanoate;DS 101;FC 1015;FC143;FX 1006;Fluorad FC 143;Perfluorooctanoic acid ammonium salt;Unidyne DS101;
PSA 40.54000
LogP 4.76900

Synthetic route

: 3825-26-1
ammonium perfluorooctanoate

: [MnCl(C4H8)(CHNCH(C6H3(O)(C6H3(C8F17)2)))2]

: [Mn(OC(O)C7F15)(C4H8)(CHNCH(C6H3(O)(C6H3(C8F17)2)))2]

Conditions

Conditions	Yield
In diethyl ether complex (0.07 mmol) dissolved in ethanol/trifluorotoluene (1/1 (v/v)), C7F15COONH4 (0.5 mmol) added, stirred at room temp. for 4 h, evapd.; dissolved (n-perfluorooctane), washed (water), dried (MgSO4, vac.), elem. anal.;	68%

Ammonium perfluorooctanoate Chemical Properties

Molecular Formula: C₈H₄F₁₅NO₂
Molar mass: 431.1 g/mol
EINECS: 223-320-4
Flash Point: 62.1 °C
Boiling Point: 188 °C at 760 mmHg
Vapour Pressure: 0.274 mmHg at 25°C
Melting point: 163-165(dec.)
Solubility: H₂O: 0.1 g/mL, clear, colorless
Product categories of Ammonium perfluorooctanoate (3825-26-1): Fluorochemical Surfactants;Organics;Functional Materials
Structure of Ammonium perfluorooctanoate (3825-26-1):

H-Bond Donor: 2
H-Bond Acceptor: 18
Systematic Name: Ammonia; 2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-pentadecafluorooctanoic acid
SMILES: FC(F)(C(F)(F)C(=O)O)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F.N
InChI: InChI=1/C8HF15O2.H3N/c9-2(10,1(24)25)3(11,12)4(13,14)5(15,16)6(17,18)7(19,20)8(21,22)23;/h(H,24,25);1H3
InChIKey: YOALFLHFSFEMLP-UHFFFAOYAF
Std. InChI: InChI=1S/C8HF15O2.H3N/c9-2(10,1(24)25)3(11,12)4(13,14)5(15,16)6(17,18)7(19,20)8(21,22)23;/h(H,24,25);1H3
Std. InChIKey: YOALFLHFSFEMLP-UHFFFAOYSA-N

Ammonium perfluorooctanoate Toxicity Data With Reference

1.	skn-rbt 500 mg MOD	TXAPA9 Toxicology and Applied Pharmacology. 81 (1985),348.
2.	eye-rbt 500 mg/24 H MOD	AIHAAP American Industrial Hygiene Association Journal. 41 (1980),576.
3.	orl-rat LD50:430 mg/kg	AIHAAP American Industrial Hygiene Association Journal. 41 (1980),576.
4.	ihl-rat LC50:980 mg/m3/4 H	FCTOD7 Food and Chemical Toxicology. 24 (1986),1325.
5.	skn-rat LD50:7 g/kg	TXAPA9 Toxicology and Applied Pharmacology. 81 (1985),348.
6.	skn-rbt LD50:4300 mg/kg	TXAPA9 Toxicology and Applied Pharmacology. 81 (1985),348.

Ammonium perfluorooctanoate Consensus Reports

Reported in EPA TSCA Inventory.

Ammonium perfluorooctanoate Safety Profile

Confirmed carcinogen. Poison by inhalation. Moderately toxic by ingestion. An eye and skin irritant. Experimental reproductive effects. When heated to decomposition it emits toxic fumes of F⁻ and NH₃.

Hazard Codes: Xn,Xi
Risk Statements:
20: Harmful by inhalation
22: Harmful if swallowed
36: Irritating to the eyes
38: Irritating to the skin
Safety Statements:
26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
36: Wear suitable protective clothing

Ammonium perfluorooctanoate Standards and Recommendations

ACGIH TLV: 0.01 mg/m³; Animal Carcinogen

Ammonium perfluorooctanoate Specification

Ammonium perfluorooctanoate (3825-26-1) also can be called Perfluoroammonium octanoate ; Fluorad FC 143 ; Ammonium pentadecafluorooctanoate and Ammonium perfluorocaprylate .

Product Name

PERFLUOROOCTANOIC ACID AMMONIUM SALT