Product Name

  • Name

    BENZO(K)FLUORANTHENE

  • EINECS 205-916-6
  • CAS No. 207-08-9
  • Article Data49
  • CAS DataBase
  • Density 1.286 g/cm3
  • Solubility 1.09 μg/L at 25 °C (de Maagd et al., 1998)
  • Melting Point 215-217 °C(lit.)
  • Formula C20H12
  • Boiling Point 480 °C
  • Molecular Weight 252.315
  • Flash Point 228.6 °C
  • Transport Information UN 2811 6
  • Appearance YELLOW CRYSTALS
  • Safety Confirmed carcinogen with experimental tumorigenic data. Mutation data reported. When heated to decomposition it emits acrid smoke and irritating fumes.

    Analytical Methods:

       

    For occupational chemical analysis use NIOSH: Polynuclear Aromatic Hydrocarbons (HPLC), 5506; (GC), 5515.

  • Risk Codes 45-50/53
  • Molecular Structure Molecular Structure of 207-08-9 (BENZO(K)FLUORANTHENE)
  • Hazard Symbols Confirmed carcinogen.
  • Synonyms 11,12-Benzofluoranthene;2,3,1',8'-Binaphthylene; 8,9-Benzfluoranthene; 8,9-Benzofluoranthene;Dibenzo[b,jk]fluorene
  • PSA 0.00000
  • LogP 5.64040

Synthetic route

C20H14O

C20H14O

Benzo[k]fluoranthene
207-08-9

Benzo[k]fluoranthene

Conditions
ConditionsYield
With zinc(II) chloride In acetic anhydride at 130℃; for 0.5h;88%
2-hydroxy-3-(1-naphthyl)naphthalene triflate
146746-48-7

2-hydroxy-3-(1-naphthyl)naphthalene triflate

Benzo[k]fluoranthene
207-08-9

Benzo[k]fluoranthene

Conditions
ConditionsYield
With 1,8-diazabicyclo[5.4.0]undec-7-ene; lithium chloride; bis(triphenylphosphine)palladium(II)-chloride In N,N-dimethyl-formamide at 120℃; for 3h;64%
7-(methylthio)benzo[k]fluoranthene

7-(methylthio)benzo[k]fluoranthene

Benzo[k]fluoranthene
207-08-9

Benzo[k]fluoranthene

Conditions
ConditionsYield
Raney Ni (W2) In ethanol for 6h; Heating;61%
(E)-1-ethynyl-8-styrylnaphthalene

(E)-1-ethynyl-8-styrylnaphthalene

Benzo[k]fluoranthene
207-08-9

Benzo[k]fluoranthene

Conditions
ConditionsYield
In toluene at 140℃; for 24h; Sealed tube;54%
acenaphthenequinone monoxime
33489-49-5

acenaphthenequinone monoxime

o-xylylene(bistriphenylphospine) dibromide
1519-46-6

o-xylylene(bistriphenylphospine) dibromide

Benzo[k]fluoranthene
207-08-9

Benzo[k]fluoranthene

Conditions
ConditionsYield
With lithium ethoxide In N,N-dimethyl-formamide 1.) warming to 90 deg C, 5h; 2.)25 deg C, 12h;32%
azuleno<1,2-a>acenaphthylene
33084-86-5

azuleno<1,2-a>acenaphthylene

A

Benzo[k]fluoranthene
207-08-9

Benzo[k]fluoranthene

B

Benzo[j]fluoranthene
205-82-3

Benzo[j]fluoranthene

Conditions
ConditionsYield
In benzene at 600℃;A 14%
B 28%
[1,2′-binaphthalen]-8-yl nonafluorobutanesulfonate

[1,2′-binaphthalen]-8-yl nonafluorobutanesulfonate

A

Benzo[k]fluoranthene
207-08-9

Benzo[k]fluoranthene

B

Benzo[j]fluoranthene
205-82-3

Benzo[j]fluoranthene

Conditions
ConditionsYield
With dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; potassium phosphate; tris-(dibenzylideneacetone)dipalladium(0); 1-Adamantanecarboxylic acid In N,N-dimethyl acetamide at 110℃; for 24h; Inert atmosphere;A 26%
B 8%
o-xylylene(bistriphenylphospine) dibromide
1519-46-6

o-xylylene(bistriphenylphospine) dibromide

Benzo[k]fluoranthene
207-08-9

Benzo[k]fluoranthene

Conditions
ConditionsYield
With sodium methylate In N,N-dimethyl-formamide at 0 - 20℃; for 3.5h; Wittig Olefination; Inert atmosphere;19%
With lithium hydroxide In dichloromethane for 48h; Ambient temperature;18%

Benzo[k]fluoranthene
207-08-9

Benzo[k]fluoranthene

Conditions
ConditionsYield
With selenium at 340℃;
Benzo[j]fluoranthene
205-82-3

Benzo[j]fluoranthene

A

Benzo[k]fluoranthene
207-08-9

Benzo[k]fluoranthene

B

PERYLENE

PERYLENE

C

cyclopenta[c,d]pyrene
27208-37-3

cyclopenta[c,d]pyrene

D

benzo[ghi]fluoranthene
203-12-3

benzo[ghi]fluoranthene

Conditions
ConditionsYield
at 1200℃; under 0.01 Torr; flash vacuum thermolysis; Further byproducts given;A 15 % Chromat.
B 7 % Chromat.
C 7 % Chromat.
D 4 % Chromat.
Benzo[j]fluoranthene
205-82-3

Benzo[j]fluoranthene

A

Benzo[k]fluoranthene
207-08-9

Benzo[k]fluoranthene

B

PERYLENE
198-55-0

PERYLENE

C

cyclopenta[c,d]pyrene
27208-37-3

cyclopenta[c,d]pyrene

D

cyclopentacepyrylene
98791-43-6

cyclopentacepyrylene

Conditions
ConditionsYield
at 1200℃; under 0.01 Torr; flash vacuum thermolysis; Further byproducts given;A 15 % Chromat.
B 7 % Chromat.
C 7 % Chromat.
D 6 % Chromat.
at 1200℃; under 0.01 Torr; flash vacuum thermolysis; Further byproducts given;A 15 % Chromat.
B 13 % Chromat.
C 7 % Chromat.
D 6 % Chromat.
Benzo[j]fluoranthene
205-82-3

Benzo[j]fluoranthene

A

Benzo[k]fluoranthene
207-08-9

Benzo[k]fluoranthene

B

PERYLENE
198-55-0

PERYLENE

C

benzo[ghi]fluoranthene
203-12-3

benzo[ghi]fluoranthene

D

benzacephenanthrylene
216-48-8

benzacephenanthrylene

Conditions
ConditionsYield
at 1200℃; under 0.01 Torr; flash vacuum thermolysis; Further byproducts given;A 15 % Chromat.
B 7 % Chromat.
C 4 % Chromat.
D 4 % Chromat.
Benzo[j]fluoranthene
205-82-3

Benzo[j]fluoranthene

A

Benzo[k]fluoranthene
207-08-9

Benzo[k]fluoranthene

B

PERYLENE
198-55-0

PERYLENE

C

benzacephenanthrylene
216-48-8

benzacephenanthrylene

D

cyclopentacepyrylene
98791-43-6

cyclopentacepyrylene

Conditions
ConditionsYield
at 1200℃; under 0.01 Torr; flash vacuum thermolysis; Further byproducts given;A 15 % Chromat.
B 7 % Chromat.
C 4 % Chromat.
D 6 % Chromat.
U.S. low sulfur petroleum diesel fuel

U.S. low sulfur petroleum diesel fuel

Benzo[k]fluoranthene
207-08-9

Benzo[k]fluoranthene

Conditions
ConditionsYield
combustion; Formation of xenobiotics;
100 percent soy methyl ester biodiesel fuel

100 percent soy methyl ester biodiesel fuel

Benzo[k]fluoranthene
207-08-9

Benzo[k]fluoranthene

Conditions
ConditionsYield
combustion; Formation of xenobiotics;
methyl chloride; methane; mixture of

methyl chloride; methane; mixture of

Benzo[k]fluoranthene
207-08-9

Benzo[k]fluoranthene

Conditions
ConditionsYield
With air Oxidation; Formation of xenobiotics;
polystyrene

polystyrene

A

phenanthridine
229-87-8

phenanthridine

B

Benzo[k]fluoranthene
207-08-9

Benzo[k]fluoranthene

C

PERYLENE
198-55-0

PERYLENE

D

cyclopenta[c,d]pyrene
27208-37-3

cyclopenta[c,d]pyrene

Conditions
ConditionsYield
With air at 900℃; Condensation; combustion; pyrolysis; PAH formation; Formation of xenobiotics; Further byproducts given. Title compound not separated from byproducts;A 0.04 mg
B 0.04 mg
C 0.12 mg
D 0.03 mg
polystyrene

polystyrene

A

11H-benzo[a]carbazole
239-01-0

11H-benzo[a]carbazole

B

Benzo[k]fluoranthene
207-08-9

Benzo[k]fluoranthene

C

Tetracen
92-24-0

Tetracen

D

cyclopenta[c,d]pyrene
27208-37-3

cyclopenta[c,d]pyrene

Conditions
ConditionsYield
With air at 900℃; Condensation; combustion; pyrolysis; PAH formation; Formation of xenobiotics; Further byproducts given. Title compound not separated from byproducts;A 0.21 mg
B 0.04 mg
C 0.45 mg
D 0.03 mg
polyethylene

polyethylene

A

2,2'-binaphthalene
612-78-2

2,2'-binaphthalene

B

Benzo[k]fluoranthene
207-08-9

Benzo[k]fluoranthene

C

benzopyrene
50-32-8

benzopyrene

D

1-phenyl phenanthrene
4325-76-2

1-phenyl phenanthrene

Conditions
ConditionsYield
With air at 600 - 900℃; Oxidation; Formation of xenobiotics; Further byproducts given;
waste wood chips

waste wood chips

A

benzo[e]acephenanthrylene
205-99-2

benzo[e]acephenanthrylene

B

Benzo[k]fluoranthene
207-08-9

Benzo[k]fluoranthene

C

chrysene
218-01-9

chrysene

D

benzo[e]pyrene
192-97-2

benzo[e]pyrene

Conditions
ConditionsYield
With air Oxidation; Formation of xenobiotics; Further byproducts given;
benzo<k>fluoranthene-dicarboxylic acid-(7.12)-diamide

benzo<k>fluoranthene-dicarboxylic acid-(7.12)-diamide

Benzo[k]fluoranthene
207-08-9

Benzo[k]fluoranthene

Conditions
ConditionsYield
With phosphoric acid at 150℃;
binaphthyl-(1.2')

binaphthyl-(1.2')

A

Benzo[k]fluoranthene
207-08-9

Benzo[k]fluoranthene

B

Benzo[j]fluoranthene
205-82-3

Benzo[j]fluoranthene

Conditions
ConditionsYield
With chromium corundum at 500℃;
1-(naphthalen-2-yl)naphthalene
4325-74-0

1-(naphthalen-2-yl)naphthalene

chromium oxide-aluminium oxide

chromium oxide-aluminium oxide

A

Benzo[k]fluoranthene
207-08-9

Benzo[k]fluoranthene

B

Benzo[j]fluoranthene
205-82-3

Benzo[j]fluoranthene

Conditions
ConditionsYield
at 500℃;
phosphoric acid
86119-84-8, 7664-38-2

phosphoric acid

benzo[k]fluoranthene-7,12-dicarboxamide
875241-60-4

benzo[k]fluoranthene-7,12-dicarboxamide

Benzo[k]fluoranthene
207-08-9

Benzo[k]fluoranthene

Conditions
ConditionsYield
at 150℃;
Eucalyptus grandis wood

Eucalyptus grandis wood

Benzo[k]fluoranthene
207-08-9

Benzo[k]fluoranthene

Conditions
ConditionsYield
Decomposition; Formation of xenobiotics; pyrolysis;
Pennzoil Perfomax SAE 5W-40 synthetic oil

Pennzoil Perfomax SAE 5W-40 synthetic oil

leaded gasoline 91 octane

leaded gasoline 91 octane

A

benzo[e]acephenanthrylene
205-99-2

benzo[e]acephenanthrylene

B

Benzo[k]fluoranthene
207-08-9

Benzo[k]fluoranthene

C

fluoranthene
206-44-0

fluoranthene

D

benzopyrene
50-32-8

benzopyrene

Conditions
ConditionsYield
With air Oxidation; Formation of xenobiotics; Further byproducts given. Title compound not separated from byproducts;
Mogul Forte GX SAE 15W-40 mineral oil

Mogul Forte GX SAE 15W-40 mineral oil

leaded gasoline 91 octane

leaded gasoline 91 octane

A

benzo[e]acephenanthrylene
205-99-2

benzo[e]acephenanthrylene

B

Benzo[k]fluoranthene
207-08-9

Benzo[k]fluoranthene

C

fluoranthene
206-44-0

fluoranthene

D

benzopyrene
50-32-8

benzopyrene

Conditions
ConditionsYield
With air Oxidation; Formation of xenobiotics; Further byproducts given. Title compound not separated from byproducts;
artificial solid municipal waste

artificial solid municipal waste

A

benzo[e]acephenanthrylene
205-99-2

benzo[e]acephenanthrylene

B

Benzo[k]fluoranthene
207-08-9

Benzo[k]fluoranthene

C

phenanthrene
85-01-8

phenanthrene

D

fluoranthene
206-44-0

fluoranthene

Conditions
ConditionsYield
With air at 780℃; Formation of xenobiotics; Further byproducts given. Title compound not separated from byproducts;
tyre rubber

tyre rubber

A

benzo[e]acephenanthrylene
205-99-2

benzo[e]acephenanthrylene

B

Benzo[k]fluoranthene
207-08-9

Benzo[k]fluoranthene

C

fluoranthene
206-44-0

fluoranthene

D

benz[a]anthracene
56-55-3

benz[a]anthracene

Conditions
ConditionsYield
With carbon dioxide at 900℃; Formation of xenobiotics; Further byproducts given. Title compound not separated from byproducts;
Benzo[k]fluoranthene
207-08-9

Benzo[k]fluoranthene

acetyl chloride
75-36-5

acetyl chloride

3-acetylbenzo[k]fluoranthene
1433843-55-0

3-acetylbenzo[k]fluoranthene

Conditions
ConditionsYield
With aluminum (III) chloride In dichloromethane at -5 - 0℃; Friedel-Crafts Acylation;68%
Benzo[k]fluoranthene
207-08-9

Benzo[k]fluoranthene

A

benzo[k]fluoranthene-7,12-dione
112575-90-3

benzo[k]fluoranthene-7,12-dione

B

Benzo[k]fluoranthene-2,3-dione
112575-91-4

Benzo[k]fluoranthene-2,3-dione

Conditions
ConditionsYield
With cerium(IV) ammonium sulphate; sulfuric acid In acetonitrile for 5h; Ambient temperature;A 28%
B 10%
Benzo[k]fluoranthene
207-08-9

Benzo[k]fluoranthene

benzo[k]fluoranthene-7,12-dione
112575-90-3

benzo[k]fluoranthene-7,12-dione

Conditions
ConditionsYield
With chromium(VI) oxide; acetic acid
Benzo[k]fluoranthene
207-08-9

Benzo[k]fluoranthene

2,2-Dimethylmalonyl chloride
5659-93-8

2,2-Dimethylmalonyl chloride

2,2-dimethyl-2H-benzo[cd,k]fluoranthene-1,3-dione
325148-65-0

2,2-dimethyl-2H-benzo[cd,k]fluoranthene-1,3-dione

Benzo[k]fluoranthene
207-08-9

Benzo[k]fluoranthene

A

Benzo[j]fluoranthene
205-82-3

Benzo[j]fluoranthene

B

Benzacephenanthrylene
212-41-9

Benzacephenanthrylene

Conditions
ConditionsYield
at 1200℃; under 0.01 Torr; flash vacuum thermolysis;A 11 % Chromat.
B 5 % Chromat.

Benzo[k]fluoranthene Chemical Properties

Molecular Formula: C20H12
Molar mass: 252.31 g/mol
EINECS: 205-916-6
Density: 1.286 g/cm3
Flash Point: 228.6 °C
Index of Refraction: 1.887
Boiling Point: 480 °C at 760 mmHg
Vapour Pressure: 6.55E-09 mmHg at 25°C
Melting point: 215-217 °C(lit.)
Storage temp: Approx 4°C
Water solubility: Insoluble
Appearance: Pale yellow needles or yellow crystalline solid
Product categories: Detection;Fluorescent Probes, Labels, Particles and Stains;Derivatization agents;Environmental Standards;Luminescent Compounds;Volatiles/ Semivolatiles;Chemical Class;Hydrocarbons;Biochemicals and Reagents
Structure of Benzo[k]fluoranthene (207-08-9):

XLogP3-AA: 6.4
H-Bond Donor: 0
H-Bond Acceptor: 0
IUPAC Name: Benzo[k]fluoranthene
Canonical SMILES: C1=CC=C2C=C3C4=CC=CC5=C4C(=CC=C5)C3=CC2=C1
InChI: InChI=1S/C20H12/c1-2-6-15-12-19-17-10-4-8-13-7-3-9-16(20(13)17)18(19)11-
14(15)5-1/h1-12H 
InChIKey: HAXBIWFMXWRORI-UHFFFAOYSA-N

Benzo[k]fluoranthene Toxicity Data With Reference

1.    

mma-sat 10 µg/plate

    CNREA8    Cancer Research. 40 (1980),4528.

Carcinogenicity of Benzo[k]fluoranthene (207-08-9) hasn't been listed as a carcinogen by NTP, IARC,ACGIH, or CA Prop 65.You can see actual entry in RTECS for complete information.

Benzo[k]fluoranthene Consensus Reports

NTP 10th Report on Carcinogens. IARC Cancer Review: Group 2B IMEMDT    IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 7 (1987),p. 56.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) ; Animal Sufficient Evidence IMEMDT    IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 32 (1983),p. 163.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) ; Human No Adequate Data IMEMDT    IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 32 (1983),p. 163.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) .

Benzo[k]fluoranthene Safety Profile

Confirmed carcinogen with experimental tumorigenic data. Mutation data reported. When heated to decomposition it emits acrid smoke and irritating fumes.
 

Hazard Codes: T,N,Xn,F
Risk Statements:
11:  Highly Flammable
36:  Irritating to the eyes
38:  Irritating to the skin
40:  Limited evidence of a carcinogenic effect
45:  May cause cancer
50:  Very Toxic to aquatic organisms
53:  May cause long-term adverse effects in the aquatic environment
65:  Harmful: May cause lung damage if swallowed
66:  Repeated exposure may cause skin dryness or cracking
67:  Vapors may cause drowsiness and dizziness
Safety Statements:
26:  In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
36:  Wear suitable protective clothing
37:  Wear suitable gloves
45:  In case of accident or if you feel unwell, seek medical advice immediately (show label where possible)
53:  Avoid exposure - obtain special instruction before use
60:  This material and/or its container must be disposed of as hazardous waste
61:  Avoid release to the environment. Refer to special instructions safety data sheet
62:  If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label

Benzo[k]fluoranthene Analytical Methods

For occupational chemical analysis use NIOSH: Polynuclear Aromatic Hydrocarbons (HPLC), 5506; (GC), 5515.

Benzo[k]fluoranthene Specification

 Benzo[k]fluoranthene (207-08-9) also can be called 11,12-Benzofluoranthene ; 8,9-Benzofluoranthene ;  8,9-Benzfluoranthene ; 11,12-Benzo(k)fluoranthene and Dibenzo[b,jk]fluorene .It is hazardous,so the first aid measures and others should be known.Such as: When on the skin: first,should  flush skin with plenty of water immediately for at least 15 minutes while removing contaminated clothing. Secondly,Get shoesmedical aid . Or in the eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids.Then get medical aid soon.While ,it's Inhaled: Remove from exposure and move to fresh air immediately.Give artificial respiration while not breathing. When breathing is difficult, give oxygen. And as soon as to get medical aid. Then you have the ingesting of the product : Wash mouth out with water,and get medical aid immediately.
In addition, Benzo[k]fluoranthene (207-08-9) can be stable under normal temperature and pressure conditions.It is not compatible with strong oxidizing agents, and you must not take it with incompatible materials.And also prevent it to broken down into hazardous decomposition products: carbon dioxide, carbon monoxide.

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