1-METHYLCYCLOPROPANE-1-CARBOXYLIC ACID METHYL ESTER

The CAS register number of Methyl 1-methylcyclopropane-1-carboxylate is 6206-25-3. It also can be called as 1-Methylcyclopropane-1-carboxylic acid methyl ester and the systematic name about this chemical is methyl 1-methylcyclopropanecarboxylate. The molecular formula about this chemical is C₆H₁₀O₂ and the molecular weight is 114.14. It belongs to the following product categories, such as Cyclopropanes; Simple 3-Membered Ring Compounds and so on.

Physical properties about Methyl 1-methylcyclopropane-1-carboxylate are: (1)ACD/LogP: 1.09; (2)ACD/LogD (pH 5.5): 1.08; (3)ACD/LogD (pH 7.4): 1.08; (4)ACD/BCF (pH 5.5): 3.93; (5)ACD/BCF (pH 7.4): 3.93; (6)ACD/KOC (pH 5.5): 92.69; (7)ACD/KOC (pH 7.4): 92.69; (8)#H bond acceptors: 2; (9)#Freely Rotating Bonds: 2; (10)Polar Surface Area: 26.3Ų; (11)Index of Refraction: 1.45; (12)Molar Refractivity: 29.39 cm³; (13)Molar Volume: 109.2 cm³; (14)Polarizability: 11.65x10^-24cm³; (15)Surface Tension: 33.2 dyne/cm; (16)Enthalpy of Vaporization: 35.73 kJ/mol; (17)Boiling Point: 119.1 °C at 760 mmHg; (18)Vapour Pressure: 16.2 mmHg at 25°C.

Preparation: this chemical can be prepared by diazomethane and 2-methyl-acrylic acid methyl ester. This reaction will also produce 3-methyl-4,5-dihydro-3H-pyrazole-3-carboxylic acid methyl ester. This reaction will need catalyst Pd(acac)₂ and solvent diethyl ether. The reaction temperature is 0 ℃. The yield is about 76%.

When you are using this chemical, please be cautious about it as the following:
This chemical is flammable and it is harmful by inhalation, in contact with skin and if swallowed. When you are using it, wear suitable protective clothing, gloves and eye/face protection, you need keep away from sources of ignition. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

You can still convert the following datas into molecular structure:
(1)SMILES: O=C(OC)C1(C)CC1
(2)InChI: InChI=1/C6H10O2/c1-6(3-4-6)5(7)8-2/h3-4H2,1-2H3
(3)InChIKey: COHFTBWCEOBGOR-UHFFFAOYAJ
(4)Std. InChI: InChI=1S/C6H10O2/c1-6(3-4-6)5(7)8-2/h3-4H2,1-2H3
(5)Std. InChIKey: COHFTBWCEOBGOR-UHFFFAOYSA-N