Potassium nonafluoro-1-butanesulfonate supplier

Name
Potassium nonafluoro-1-butanesulfonate
EINECS 249-616-3
CAS No. 29420-49-3
Article Data8
CAS DataBase
Density 0.69 g/cm³
Solubility
Melting Point >300 °C(lit.)
Formula C₄F₉KO₃S
Boiling Point >400°C
Molecular Weight 338.192
Flash Point
Transport Information
Appearance
Safety 26-36
Risk Codes 36/37/38
Molecular Structure
Hazard Symbols Xi,C
Synonyms 1-Butanesulfonicacid, 1,1,2,2,3,3,4,4,4-nonafluoro-, potassium salt (8CI,9CI);Bayowet C 4;Biowet C 4;Eftop KFBS;F 114P;FR 2025;FR 2225;Flutel RM 65;K-NONA;KFBS;Megafac F 114;Megafac F 114P;Megafac F 411;Perfluorobutanesulfonicacid potassium salt;Potassium nonaflate;Potassium nonafluorobutanesulfonate;RM 65;FC-98;Perfluorobutansulfonic acid;
PSA 65.58000
LogP 3.03810

Synthetic route

: 375-72-4
Nonafluorobutanesulfonyl fluoride

: 29420-49-3
potassium nonaflate

Conditions

Conditions	Yield
With potassium hydroxide; calcium oxide	96%
With KOH; CaO	96%

: 60-35-5
acetamide

: 375-72-4
Nonafluorobutanesulfonyl fluoride

A: potassium salt of octafluorobutane sulphonic acid

B: C6H3F9NO3S(1-)*K(1+)

C: 29420-49-3
potassium nonaflate

Conditions

Conditions	Yield
With potassium phosphate In N,N-dimethyl-formamide at 20℃;	A n/a B n/a C 75%

...Expand

: 375-72-4
Nonafluorobutanesulfonyl fluoride

: potassium hydroxide

: 29420-49-3
potassium nonaflate

Conditions

Conditions	Yield
byproducts: HF;

: 375-73-5
perfluorobutanesulfonic acid

: potassium hydroxide

: 29420-49-3
potassium nonaflate

Conditions

Conditions	Yield
byproducts: H2O;

: 1,3-bis[(1R,2S,5R)-(-)-menthoxymethyl]imidazolium chloride

: 29420-49-3
potassium nonaflate

: 1,3-bis[(1R,2S,5R)-(-)-menthoxymethyl]imidazolium perfluorobutanesulfonate

Conditions

Conditions	Yield
In methanol at 40℃; for 24h;	99.5%

: 29420-49-3
potassium nonaflate

: 375-73-5
perfluorobutanesulfonic acid

Conditions

Conditions	Yield
With Amberlite IR-100 (H-form) ion exchange column In methanol	99%
In water passing over a cationic ion exchange resin;	>99
In water passing over a cationic ion exchange resin;	>99

: 29420-49-3
potassium nonaflate

: 98-80-6
phenylboronic acid

: 25628-11-9
phenyl 1,1,2,2,3,3,4,4,4-nonafluoro-1-butanesulfonate

Conditions

Conditions	Yield
With C18H6BiF15O5S2; sodium phosphate; 2,6-dichloro-1-fluoropyridin-1-ium tetrafluoroborate In chloroform at 60℃; for 16h; Catalytic behavior; Reagent/catalyst; Molecular sieve; Inert atmosphere;	97%

: 29420-49-3
potassium nonaflate

: tetrakis(tert-butylamino)phosphonium chloride

: tetrakis(tert-butylamino)phosphonium nonafluorobutanesulfonate

Conditions

Conditions	Yield
In water	96%

: 798553-21-6
4-(trimethylsilyl)phenyl trifluoromethanesulfonate

: 29420-49-3
potassium nonaflate

: 4-(trimethylsilyl)phenyl nonafluorobutane-1-sulfonate

Conditions

Conditions	Yield
With C18H6BiF15O5S2; sodium phosphate; 2,6-dichloro-1-fluoropyridin-1-ium tetrafluoroborate In chloroform at 60℃; for 16h; Molecular sieve; Inert atmosphere;	96%

: 23906-97-0
tetra-n-octylphosphonium bromide

: 29420-49-3
potassium nonaflate

: tetraoctylphosphonium nonafluorobutane-1-sulfonate

Conditions

Conditions	Yield
In dichloromethane; water	96%

: 1354971-75-7
1-hexadecyl-3-(6-hydroxyhexyl)imidazolium chloride

: 29420-49-3
potassium nonaflate

: 1354971-80-4
C4F9O3S(1-)*C25H49N2O(1+)

Conditions

Conditions	Yield
In dichloromethane; water	95%

: 16419-60-6
2-Methylphenylboronic acid

: 29420-49-3
potassium nonaflate

: 42096-33-3
o-tolyl 1,1,2,2,3,3,4,4,4-nonafluorobutane-1-sulfonate

Conditions

Conditions	Yield
With C18H6BiF15O5S2; sodium phosphate; 2,6-dichloro-1-fluoropyridin-1-ium tetrafluoroborate In chloroform at 60℃; for 16h; Molecular sieve; Inert atmosphere;	93%

: 1,3-didodecyl-2-undecylimidazolium bromide

: 29420-49-3
potassium nonaflate

: nonafluorobutanesulfonic acid-1,3-didodecyl-2-undecylimidazolium

Conditions

Conditions	Yield
In ethanol; water for 1h; Reflux;	92.6%

: 1,3-dioctadecyl-2-heptadecylimidazolium bromide

: 29420-49-3
potassium nonaflate

: nonafluorobutanesulfonate 1,3-dioctadecyl-2-heptadecylimidazolium

Conditions

Conditions	Yield
In ethanol; water for 1h; Reflux;	92.4%

: 50-00-0
formaldehyd

: Co(C3H8N2O2)(C2H8N2)2(3+)*3Cl(1-)*H2O = [Co(C3H8N2O2)(C2H8N2)2]Cl3*H2O

: 29420-49-3
potassium nonaflate

: Co(C5H12N2O2)(C2H8N2)2(3+)*3CF3(CF2)3SO3(1-) = [Co(C5H12N2O2)(C2H8N2)2](CF3(CF2)3SO3)3

Conditions

Conditions	Yield
With HOAc/NaOAc; NaBH3CN In water addn. of aq. 37% HCHO to a stirred soln. of Co complex in HOAc/NaOAc/H2O, slow addn. of NaBH3CN in H2O, stirring (30 min), dilution with H2O; chromy. (elution with a gradient of 1-3 M HCl), concn. to dryness, redissoln. (H2O), slow add. of an almost boiling soln. of CF3(CF2)3SO3K in H2O, stirring (ice-cooling, 1 h), collection, washing (ice-water), drying(50°C); elem. anal.;	92%

Yield

With HOAc/NaOAc; NaBH3CN In water addn. of aq. 37% HCHO to a stirred soln. of Co complex in HOAc/NaOAc/H2O, slow addn. of NaBH3CN in H2O, stirring (30 min), dilution with H2O; chromy. (elution with a gradient of 1-3 M HCl), concn. to dryness, redissoln. (H2O), slow add. of an almost boiling soln. of CF3(CF2)3SO3K in H2O, stirring (ice-cooling, 1 h), collection, washing (ice-water), drying(50°C); elem. anal.;

92%

...Expand

: 29420-49-3
potassium nonaflate

: 1-octyl-3-methyl-imidazolium bromide

: 1-methyl-3-octylimidazolium nonafluorobutanesulfonate

Conditions

Conditions	Yield
In acetone at 20℃; for 48h;	92%

: 29420-49-3
potassium nonaflate

: 1-(2-ethoxy-2-oxoethyl)-1-methylpyrrolidinium chloride

: 1-(2-ethoxy-2-oxoethyl)-1-methyl-pyrrolidinium nonafluorobutanesulfonate

Conditions

Conditions	Yield
In dichloromethane at 20℃; for 48h;	92%

: 29420-49-3
potassium nonaflate

: 166663-45-2
4-(2-phenylethynyl)phenyl trifluoromethanesulfonate

: 4-(phenylethynyl)phenyl nonafluorobutane-1-sulfonate

Conditions

Conditions	Yield
With C18H6BiF15O5S2; sodium phosphate; 2,6-dichloro-1-fluoropyridin-1-ium tetrafluoroborate In chloroform at 60℃; for 16h; Molecular sieve; Inert atmosphere;	92%

: 29420-49-3
potassium nonaflate

: 1-oxo-3,4-dihydro-1H-2-oxa-4a-azoniaanthracene bromide

: 1-oxo-3,4-dihydro-1H-2-oxa-4a-azonia-anthracene; 1,1,2,2,3,3,4,4,4-nonafluoro-butane-1-sulfonate

Conditions

Conditions	Yield
In ethanol for 12h; Heating;	91%

: 29420-49-3
potassium nonaflate

: 64697-40-1
1-methyl-3-octylimidazol-3-ium chloride

: 1-methyl-3-octylimidazolium nonafluorobutanesulfonate

Conditions

Conditions	Yield
In acetonitrile	91%

: 366-18-7
[2,2]bipyridinyl

: ruthenium(III) chloride trihydrate

: 29420-49-3
potassium nonaflate

: [Ru(bpy)3][SO3C4F9]2

Conditions

Conditions	Yield
Stage #1: [2,2]bipyridinyl; ruthenium(III) chloride trihydrate With ethylene glycol at 180℃; for 3h; Schlenk technique; Inert atmosphere; Stage #2: potassium nonaflate at 20℃; Schlenk technique; Inert atmosphere;	91%

...Expand

: 112400-86-9
1-n-butyl-4-methylpyridinium chloride

: 29420-49-3
potassium nonaflate

: 1-butyl-4-methylpyridinium nonafluorobutylsulfonate

Conditions

Conditions	Yield
In acetonitrile	90%

: [iridium(III)(μ-chloro)(2-phenylpyridine)2]2

: 29420-49-3
potassium nonaflate

: 72914-19-3
4,4'-di-tert-butyl-2,2'-bipyridine

: C40H40IrN4(1+)*C4F9O3S(1-)

Conditions

Conditions	Yield
Stage #1: [iridium(III)(μ-chloro)(2-phenylpyridine)2]2; 4,4'-di-tert-butyl-2,2'-bipyridine With ethylene glycol at 150℃; for 17h; Schlenk technique; Inert atmosphere; Stage #2: potassium nonaflate at 20℃; Schlenk technique; Inert atmosphere;	90%

...Expand

: C25H21S2(1+)*Br(1-)

: 29420-49-3
potassium nonaflate

: 4-(phenylthio)-3-methylphenyldiphenylsulfonium perfluorobutane sulfonate

Conditions

Conditions	Yield
In dichloromethane at 20℃; for 1h;	90%

: C25H21S2(1+)*Br(1-)

: 29420-49-3
potassium nonaflate

: 75-36-5
acetyl chloride

: 4-(4-acetylphenylthio)-3-methylphenyldiphenylsulfonium perfluorobutane sulfonate

Conditions

Conditions	Yield
Stage #1: C25H21S2(1+)*Br(1-); acetyl chloride With aluminum (III) chloride In dichloromethane at 10 - 20℃; for 2h; Stage #2: potassium nonaflate In dichloromethane at 20℃; for 1h;	90%

...Expand

: 3115-68-2
tetrabutyl phosphonium bromide

: 29420-49-3
potassium nonaflate

: 220689-12-3
tetrabutylphosphonium nonafluorobutane-1-sulfonate

Conditions

Conditions	Yield
In ethanol; water at 20℃; for 0.25h; Product distribution / selectivity;	89.1%
In ethanol; water at 20℃; for 0.25h;	89.1%
In water at 20 - 80℃;	74%
In water at 20 - 85℃; for 0.25h; Product distribution / selectivity;	57.6%

: 29420-49-3
potassium nonaflate

: 1-butyl-2,3-dimethylimidazolium bromide

: 1-n-butyl-2,3-dimethylimidazolium perfluorobutylsulfonate

Conditions

Conditions	Yield
In water at 20℃; for 12h;	88%

: 870987-64-7
bis-(μ)-chlorotetrakis[2-(2’,4’-difluorophenyl)-5-trifluoromethylpyridinato]-(C2,N)diiridium(III)

: 29420-49-3
potassium nonaflate

: 72914-19-3
4,4'-di-tert-butyl-2,2'-bipyridine

: C42H34F10IrN4(1+)*C4F9O3S(1-)

Conditions

Conditions	Yield
Stage #1: bis-(μ)-chlorotetrakis[2-(2’,4’-difluorophenyl)-5-trifluoromethylpyridinato]-(C2,N)diiridium(III); 4,4'-di-tert-butyl-2,2'-bipyridine With ethylene glycol at 150℃; for 14h; Schlenk technique; Inert atmosphere; Stage #2: potassium nonaflate at 20℃; Schlenk technique; Inert atmosphere;	88%

...Expand

: C12H9F13N2S*HI

: 29420-49-3
potassium nonaflate

: 2-(1H,1H,2H,2H-perfluorooctylthio)-1-methylimidazolium perfluorobutanesulfonate

Conditions

Conditions	Yield
In water at 20℃; for 24h;	87%

: 29420-49-3
potassium nonaflate

: 3-ethoxycarbonyl-2-phenylmethylisoquinolinium bromide

: 3-ethoxycarbonyl-2-benzyl isoquinolinium 1,1,2,2,3,3,4,4,4-nonafluorobutane-1-sulfonate

Conditions

Conditions	Yield
In ethanol for 12h; Heating;	86%

: 1425925-31-0
trimethylpropylammonium hepta(isooctyl)octasilsesquioxane iodide

: 29420-49-3
potassium nonaflate

: 1425925-34-3
trimethylpropylammonium tepta(isooctyl)octasilsesquioxane nonafluoro-1-butanesulfonate

Conditions

Conditions	Yield
In water at 50℃;	86%

: C18H14FS(1+)*CF3O3S(1-)

: 29420-49-3
potassium nonaflate

: C18H14FS(1+)*C4F9O3S(1-)

Conditions

Conditions	Yield
In dichloromethane; water at 25℃; for 4h;	86%

: 107429-38-9
N,N-dimethyl-N-(n-heptyl)-N-[2-(methacryloyloxy)ethyl]ammonium bromide

: 29420-49-3
potassium nonaflate

: 1203998-93-9
[2-(methacryloyloxy)ethyl]dimethylheptylammonium nonafluoro-1-butanesulfonate

Conditions

Conditions	Yield
In water at 20 - 60℃; Inert atmosphere;	85%

Potassium nonafluoro-1-butanesulfonate Chemical Properties

Molecular Structure:

Molecular Formula: C₄F₉KO₃S
Molecular Weight: 338.1899
IUPAC Name: Potassium 1,1,2,2,3,3,4,4,4-nonafluorobutane-1-sulfonate
Synonyms of 1-Butanesulfonic acid, 1,1,2,2,3,3,4,4,4-nonafluoro-, potassium salt (CAS NO.29420-49-3): 1,1,2,2,3,3,4,4,4-Nonafluorobutane-1-sulfonic acid, potassium salt ; EINECS 249-616-3 ; 1-Butanesulfonic acid, 1,1,2,2,3,3,4,4,4-nonafluoro-, potassium salt (1:1) ; Potassium 1,1,2,2,3,3,4,4,4-nonafluorobutane-1-sulphonate
CAS NO: 29420-49-3
Product Categories: Organics
Melting point: >300 °C
H bond acceptors: 3
H bond donors: 1
Freely Rotating Bonds: 3
Polar Surface Area: 62.75 Å²

Potassium nonafluoro-1-butanesulfonate Uses

1-Butanesulfonic acid, 1,1,2,2,3,3,4,4,4-nonafluoro-, potassium salt (CAS NO.29420-49-3) is a perfluorinated anionic surfactants, widely used as a flame retardant of synthetic materials, especially polycarbonate material.

Potassium nonafluoro-1-butanesulfonate Safety Profile

Safety Information of 1-Butanesulfonic acid, 1,1,2,2,3,3,4,4,4-nonafluoro-, potassium salt (CAS NO.29420-49-3):
Hazard Codes:Xi ,C
Risk Statements:36/37/38
36/37/38:Irritating to eyes, respiratory system and skin
Safety Statements:26-36
26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
36:Wear suitable protective clothing
WGK Germany:3

Product Name

Potassium nonafluoro-1-butanesulfonate

Synthetic route

Potassium nonafluoro-1-butanesulfonate Chemical Properties

Potassium nonafluoro-1-butanesulfonate Uses

Potassium nonafluoro-1-butanesulfonate Safety Profile

Related Products

Hot Products