Encyclopedia

  • Wharton Reaction

    Wharton Reaction P. S. Wharton, D. H. Bohlen, J. Org. Chem. 26, 3615 (1961); P. S. Wharton, ibid. 4781. Reduction of α,β-epoxy ketones by hyd

  • Weiss Reaction

    Weiss Reaction U. Weiss, J. M. Edwards, Tetrahedron Letters 1968, 4885. Reaction of 1,2-dicarbonyl compounds with 3-oxoglutarates to yield cis-bicyclo[3

  • Weerman Degradation

    Weerman Degradation R. A. Weerman, Rec. Trav. Chim. 37, 1, 16 (1918). Formation of an aldose with one less carbon from an aldonic acid by a Hofmann-type

  • Wallach Rearrangement

    Wallach Rearrangement O. Wallach, L. Belli, Ber. 13, 525 (1880). Acid-catalyzed rearrangement of azoxybenzenes to p-hydroxyazobenzenes:

  • Walden Inversion

    Walden Inversion P. Walden, Ber. 28, 1287, 2766 (1895). Inversion of configuration of a chiral center in bimolecular nucleophilic substitution (SN2) rea

  • Wacker Oxidation

    Wacker Oxidation J. Smidt et al., Angew. Chem. Int. Ed. 1, 176 (1959). The oxidation of ethylene to employing palladium chloride and cupric chloride as

  • Vorbrüggen Glycosylation

    Vorbrüggen Glycosylation U. Niedballa, H. Vorbrüggen, Angew. Chem. Int. Ed. 9, 461 (1970). The reaction of silylated heterocyclic bases with p

  • von Richter Rearrangement

    von Richter Rearrangement V. von Richter, Ber. 4, 21, 459, 553 (1871). Carboxylation of para- or meta-substituted aromatic nitro compounds with cyanate

  • von Richter (Cinnoline) Synthesis

    von Richter (Cinnoline) Synthesis V. von Richter, Ber. 16, 677 (1883). Formation of cinnoline derivatives by diazotization of o-aminoarylpropiolic acids

  • von Braun Reaction

    von Braun Reaction J. von Braun, Ber. 40, 3914 (1907); 42, 2219 (1909); 44, 1250 (1911). Reaction of tertiary amines with cyanogen bromide to form disub

  • von Braun Amide Degradation

    von Braun Amide Degradation H. von Pechmann, Ber. 33, 611 (1900); J. von Braun, ibid. 37, 3210 (1904). Mechanistic study: B. A. Phil

  • Voight Amination

    Voight Amination K. Voight, J. Prakt. Chem. [2] 34, 1 (1886). Amination of benzoins with amines in the presence of phosphorus pentoxide or hydrochloric

  • Urech Hydantoin Synthesis

    Urech Hydantoin Synthesis F. Urech, Ann. 165, 99 (1873). Formation of hydantoins from α-amino acids by treatment with potassium cyanate in aqueous

  • Urech Cyanohydrin Method

    Urech Cyanohydrin Method; Ultee Cyanohydrin Method F. Urech, Ann. 164, 225 (1872); A. J. Ultee, Rec. Trav. Chim. 28, 1 (1909). Cyanohydrin formation by

  • Ullmann Reaction

    Ullmann Reaction F. Ullmann, Ann. 332, 38 (1904); F. Ullmann, P. Sponagel, Ber. 38, 2211 (1905). -mediated coupling of aryl halides. Biaryl ether synthe

  • Twitchell Process

    Twitchell Process E. Twitchell, US 601603; US 628503 (1898); DE 365522; DE 385074. Commercial process for splitting fats to and fatty acids by heating

  • Trost Desymmetrization

    Trost Desymmetrization B. M. Trost et al., J. Am. Chem. Soc. 114, 9333 (1992). Formation of an enantiomerically pure, azide or amine containing, five or

  • Trost Allylation

    Trost Allylation (Tsuji-Trost Reaction) J. Tsuji et al., Tetrahedron Letters 1965, 4387; B. M. Trost, T. J. Fullerton, J. Am. Chem. Soc. 95, 292 (1973).

  • Traube Purine Synthesis

    Traube Synthesis W. Traube, Ber. 33, 1371, 3035 (1900). Preparation of 4,5-diaminopyrimidines by introduction of the amino group into the 5-position of

  • Tishchenko Reaction

    Tishchenko Reaction L. Claisen Ber. 20, 646 (1887); V. Tishchenko, J. Russ. Phys. Chem. Soc. 38, 355, 482, 540, 547 (1906); Chem. Zentr. 1906 II, 1309, 1552, 1555, 1556.

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