Encyclopedia

  • Ruff-Fenton Degradation

    Ruff-Fenton Degradation O. Ruff, Ber. 31, 1573 (1898); 32, 550 (1899); H. J. H. Fenton, Proc. Chem. Soc. 9, 113 (1893). Shortening of the carbon chain o

  • Favorskii Rearrangement

    Favorskii Rearrangement; Wallach Degradation A. E. Favorskii, J. Prakt. Chem. 88(2), 658 (1913); O. Wallach, Ann. 414, 296 (1918). Base-catalyzed rearra

  • Hofmann Degradation

    Hofmann Degradation (Exhaustive Methylation) A. W. Hofmann, Ber. 14, 659 (1881). Formation of an olefin and a tertiary amine by pyrolysis of a quaternar

  • Evans Aldol Reaction

    Evans Aldol Reaction D. A. Evans et al., J. Am. Chem. Soc. 101, 6120 (1979); 103, 2127 (1981). Highly enantioselective aldol condensation of the chiral

  • Mislow-Evans Rearrangement

    Mislow-Evans Rearrangement P. Bickart et al., J. Am. Chem. Soc. 90, 4869 (1968); D. A. Evans et al., ibid. 93, 4956 (1971). [2,3]-Sigmatropic rearrangem

  • Étard Reaction

    Étard Reaction A. L. Étard, Compt. Rend. 90, 534 (1880); Ann. Chim. Phys. 22, 218 (1881). Oxidation of an arylmethyl group to an aldehyde

  • Eschenmoser Fragmentation

    Eschenmoser Fragmentation (Eschenmoser-Tanabe Fragmentation) A. Eschenmoser et al., Helv. Chim. Acta 50, 708 (1967); J. Schreiber et al., ibid. 2101; M. Tanabe et al., Tet

  • Eschenmoser Coupling Reaction

    Eschenmoser Coupling Reaction (Sulfide Contraction) A. Fischli, A. Eschenmoser, Angew. Chem. Int. Ed. 6, 866 (1967); M. Roth et al., Helv. Chim. Acta 54, 710 (1971).

  • Erlenmeyer-Plöchl Azlactone and Amino Acid Synthesis

    Erlenmeyer-Plöchl Azlactone and Amino Acid Synthesis E. Erlenmeyer, Ann. 275, 1 (1893); J. Plöchl, Ber. 17, 1616 (1884). Formation of azlacton

  • Volhard-Erdmann Cyclization

    Volhard-Erdmann Cyclization J. Volhard, H. Erdmann, Ber. 18, 454 (1885). Synthesis of alkyl and aryl thiophenes by cyclization of disodium succinate or

  • Wittig Reaction

    Wittig Reaction; Horner Reaction; Horner-Wadsworth-Emmons Reaction G. Wittig, U. Schöllkopf, Ber. 87, 1318 (1954); G. Wittig, W. Haag, ibid. 88, 1654 (1955).

  • Emmert Reaction

    Emmert Reaction B. Emmert, E. Asendorf, Ber. 72, 1188 (1939); B. Emmert, E. Pirot, ibid. 74, 714 (1941). Formation of pyridyldialkylcarbinols by condens

  • Emde Degradation

    Emde Degradation H. Emde, Ber. 42, 2590 (1909); Ann. 391, 88 (1912). Modification of the Hofmann degradation, q.v., method for reductive cleavage of the

  • Elbs Reaction

    Elbs Reaction K. Elbs, E. Larsen, Ber. 17, 2847 (1884). Formation of polyaromatics (eg. anthracene) by intramolecular condensation of diaryl ketones con

  • Elbs Persulfate Oxidation

    Elbs Persulfate Oxidation K. Elbs, J. Prakt. Chem. 48, 179 (1893). Hydroxylation of monophenols to predominantely p-diphenols or oxidation of methyl-sub

  • Tscherniac-Einhorn Reaction

    Tscherniac-Einhorn Reaction J. Tscherniac, DE 134979; A. Einhorn et al., Ann. 343, 207 (1905); 361, 113 (1908). Introduction of the amidomethyl group in

  • Ehrlich-Sachs Reaction

    Ehrlich-Sachs Reaction P. Ehrlich, F. Sachs, Ber. 32, 2341 (1899). Formation of N-phenylimines by the base-catalyzed condensation of compounds containin

  • Edman Degradation

    Edman Degradation P. Edman, Acta Chem. Scand. 4, 283 (1950). Cyclic degradation of peptides based on the reaction of phenylisothiocyanate with the free

  • Eastwood Reaction

    Eastwood Reaction (Eastwood Deoxygenation) G. Grank, F. W. Eastwood, Aust. J. Chem. 17, 1392 (1964). Stereospecific conversion of vicinal diols into ole

  • Dutt-Wormall Reaction

    Dutt-Wormall Reaction P. K. Dutt, H. R. Whitehead, A. Wormall, J. Chem. Soc. 119, 2088 (1921); P. K. Dutt, ibid. 125, 1463 (1924). Preparation of diazoa

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