100375-00-6

Basic information

• Product Name: Benzene, 1-bromo-4-[(phenylsulfinyl)methyl]-
• CAS NO: 100375-00-6
• Molecular Formula: C13H11BrOS
• Molecular Weight: 295.2
• Mol File: 100375-00-6.mol
• Article Data: 10

Chemical Properties

• CAS DataBase Reference: Benzene, 1-bromo-4-[(phenylsulfinyl)methyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-bromo-4-[(phenylsulfinyl)methyl]-(100375-00-6)
• EPA Substance Registry System: Benzene, 1-bromo-4-[(phenylsulfinyl)methyl]-(100375-00-6)

Safety Data

• Hazardous Substances Data: 100375-00-6(Hazardous Substances Data)

Upstream product

• 75954-35-7 phenyl p-bromobenzyl sulfide 
• 31268-20-9 bromomethyl phenyl sulfoxide 
• 5467-74-3 4-Bromophenylboronic acid 
• 930-69-8 sodium thiophenolate 
• 1193-82-4 racemic methyl phenyl sulfoxide 
• 201230-82-2 carbon monoxide 

Downstream Products

• 75954-35-7 phenyl p-bromobenzyl sulfide 

Relevant articles and documents

Green route for selective gram-scale oxidation of sulfides using tungstate/triazine-based ionic liquid immobilized on magnetic nanoparticles as a phase-transfer heterogeneous catalyst

Tungstate ions were successfully loaded onto triazine-based ionic liquid-functionalized magnetic nanoparticles through an anion exchange process. The use of triazine core for creating ionic liquid led to the immobilization of high amounts of WO4/sub

Selective oxidation of sulfides to sulfoxides and sulfones using n-butyltriphenylphosphonium dichromate (BunPPh3) 2Cr2O7 in the presence of aluminium chloride in solution and under microwave irradiation

A wide variety of sulfides are efficiently oxidized to their corresponding sulfoxides and sulfones in excellent yields using n-butyltriphenylphosphonium dichromate (BTPPDC) in the presence of aluminium chloride in acetonitrile solution and under microwave irradiation. In addition, selective oxidation of sulfides in the presence of functional groups such as a carbon-carbon double bond, ketone, oxime, aldehyde, ether, and acetal can be considered as a noteworthy advantage of this method. Copyright Taylor & Francis Inc.

Highly efficient selective oxygenation of sulfides to sulfoxides by oxalic acid dihydrate in the presence of h2o2

A highly efficient method for the oxidation of sulfides to sulfoxides using oxalic acid dihydrate in the presence of hydrogen peroxide has been developed. A versatile procedure for the oxidation of sulfides to sulfoxides without any over-oxidation to sulf

Modified o-methyl-substituted IBX: room temperature oxidation of alcohols and sulfides in common organic solvents

o-Methyl-substituted Me-IBX is the first modified analog of IBX that oxidizes alcohols in common organic solvents at room temperature, due to a composite of two factors, that is, low solubility and hypervalent twisting-promoted rate enhancement. Furthermore, the reagent is efficient for selective oxidation of sulfides to sulfoxides, a transformation that otherwise occurs only sluggishly with standard IBX. The facile synthetic accessibility and its mild as well as non-hazardous nature render Me-IBX a stable equivalent of Dess-Martin periodinane reagent in organic oxidations.