75954-35-7

Basic information

• Product Name: Benzene, 1-bromo-4-[(phenylthio)methyl]-
• Synonyms: 1-Bromo-4-(phenylsulfanylmethyl)benzene;1-Bromo-4-(phenylsulphanylmethyl)benzene
• CAS NO: 75954-35-7
• Molecular Formula: C₁₃H₁₁BrS
• Molecular Weight: 279.2
• Mol File: 75954-35-7.mol
• Article Data: 16

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Benzene, 1-bromo-4-[(phenylthio)methyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-bromo-4-[(phenylthio)methyl]-(75954-35-7)
• EPA Substance Registry System: Benzene, 1-bromo-4-[(phenylthio)methyl]-(75954-35-7)

Safety Data

• Hazardous Substances Data: 75954-35-7(Hazardous Substances Data)

Upstream product

• 589-15-1 1-bromomethyl-4-bromobenzene 
• 16532-79-9 4-Bromophenylacetonitrile 
• 930-69-8 sodium thiophenolate 
• 1515-88-4 1-bromo-4-methoxymethylbenzene 
• 20600-29-7 1-bromo-3-(phenoxymethyl)benzene 
• 20600-22-0 1-bromo-4-(phenoxymethyl)benzene 
• 28074-23-9 phenylsulfenyl bromide 
• 882-33-7 diphenyldisulfane 
• 100375-00-6 1-bromo-4-(phenylsulfinylmethyl)benzene 
• 100-58-3 phenylmagnesium bromide 
• 873-75-6 4-bromobenzenemethanol 
• 589-17-3 p-bromobenzyl chloride 
• 36719-71-8 1-phenyl-3,3-tetramethylenetriazene 
• 62-53-3 aniline 

Downstream Products

• 91110-68-8 1-bromo-4-((phenylsulfonyl)methyl)benzene 
• 100375-00-6 1-bromo-4-(phenylsulfinylmethyl)benzene 
• 106-38-7 para-bromotoluene 
• 19829-56-2 4,4'-dibromobibenzyl 
• 1122-91-4 4-bromo-benzaldehyde 
• 1332344-50-9 C₁₈H₂₂BNO₃S 
• 1332344-49-6 C₁₄H₁₅BO₂S 
• 5219-61-4 (phenylthio)acetonitrile 

Relevant articles and documents

Transition-metal-free decarboxylative thiolation of stable aliphatic carboxylates

A transition-metal-free decarboxylative thiolation protocol is reported in which primary, secondary, tertiary (hetero)aryl acetates and α-CN substituted acetates undergo the decarboxylative thiolation smoothly, to deliver a variety of functionalized aryl alkyl sulfides in moderate to excellent yields. Aryl diselenides are also amenable substrates for construction of C-Se bonds under the simple and mild reaction conditions. Moreover, the protocol is successfully applied to the late-stage modification of pharmaceutical carboxylates with satisfactory chemoselectivity and functional-group compatibility. This journal is

Photochemical, Metal-Free Sigmatropic Rearrangement Reactions of Sulfur Ylides

Sigmatropic rearrangement reactions constitute one of the most fundamental reactions of carbenes. While state-of-the-art synthetic methods require the use of expensive precious metal catalysts, the application of visible light for the photolysis of α-aryldiazoacetates is much less investigated and provides an operationally simple entry to carbenes under mild reaction conditions. Herein, we report on blue-light induced sigmatropic rearrangement reactions of sulfur compounds with α-aryldiazoacetates. This process, depending on the substitution pattern of the sulfide, opens up formal insertion reactions of carbenes into S?N, S?C, or C?H bonds.

Nano cobalt ferrite catalyzed coupling reaction of nitroarene and alkyl halide: An odorless and ligand-free rout to unsymmetrical thioether synthesis

This study describes an odorless protocol for the synthesis of unsymmetrical sulfides via cobalt ferrite (CoFe2O4) catalyzed cross-coupling reaction of nitroarenes with alkyl halides in the presence of thiourea as sulfur source under