100556-43-2

Basic information

• Product Name: methyl-[(1-phenyl-1-methyl)-prop-2-ynyl]-ether
• Synonyms: methyl-[(1-phenyl-1-methyl)-prop-2-ynyl]-ether
• CAS NO: 100556-43-2
• Molecular Weight: 160.216
• Mol File: 100556-43-2.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: methyl-[(1-phenyl-1-methyl)-prop-2-ynyl]-ether(CAS DataBase Reference)
• NIST Chemistry Reference: methyl-[(1-phenyl-1-methyl)-prop-2-ynyl]-ether(100556-43-2)
• EPA Substance Registry System: methyl-[(1-phenyl-1-methyl)-prop-2-ynyl]-ether(100556-43-2)

Safety Data

• Hazardous Substances Data: 100556-43-2(Hazardous Substances Data)

Upstream product

• 110-91-8 morpholine 
• 67-56-1 methanol 
• 77295-70-6 (4,4-dibromobut-3-en-2-yl)benzene 
• 127-66-2 2-Phenyl-3-butyn-2-ol 
• 108-91-8 cyclohexylamine 
• 111-92-2 dibutylamine 
• 120-72-9 indole 
• 98-86-2 acetophenone 

Downstream Products

• 1397746-28-9 2,6-dimethyl-2-phenyl-2H-chromene 
• 161834-69-1 9-Iodo-2-methoxy-2-phenyl-3-nonyne 
• 161834-67-9 7-Iodo-2-methoxy-2-phenyl-3-heptyne 
• 161834-55-5 7-Bromo-2-methoxy-2-phenyl-3-heptyne 
• 161834-57-7 9-Bromo-2-methoxy-2-phenyl-3-nonyne 
• 161834-56-6 8-Bromo-2-methoxy-2-phenyl-3-octyne 
• 18913-16-1 (+/-)-3-methoxy-3-phenyl-butan-2-one 

Relevant articles and documents

Construction of Chiral Tri- and Tetra-Arylmethanes Bearing Quaternary Carbon Centers: Copper-Catalyzed Enantioselective Propargylation of Indoles with Propargylic Esters

Copper-catalyzed enantioselective propargylation of indoles with propargylic esters and sequential Huisgen cycloaddition with azides lead to the construction of chiral triarylmethanes, bearing a quaternary carbon center, with high to excellent enantioselectivities. The result described herein can be used in the enantioselective preparation of a tetraarylmethane.

The coordination chemistry and reactivity of amino-dithiaphospholanes with rhodium, iridium, and ruthenium

Novel amino-dithiaphospholane complexes of ruthenium, iridium, and rhodium were synthesized, and their properties were studied. Reaction of the new amino-dithiaphospholane (RS)2PNR2′ (R = binaphthyl, R′ = CH2Ph,

2-Propynylamines from 1,1-Dibromo-1-alkenes

Easily accessible 1,1-dibromo-1-alkenes react with primary or secondary amines in a complex series of reactions to give directly N-substituted or N,N-disubstituted (1-Alkyl-1-aryl-2-propynyl)amines 5 in useful yields.This simple method avoids the isolation of intermediates (bromoacetylenes or bromoallenes) and makes a series of 2-propynylamines with an acetylenic hydrogen available.