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10060-11-4

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10060-11-4 Usage

Description

Germanium Dichloride-Dioxane Complex is a white powder chemical compound that is unstable and decomposes into polymer subchloride at low temperatures. It is derived from the reaction of germanium(II) chloride, GeCl2, with alkali hydroxides, resulting in the formation of germanium(II) hydroxide, Ge(OH)2. This hydroxide is amphiprotic, meaning it can act as both an acid and a base, and dissolves in excess alkali. The acid form, sometimes referred to as germanous acid, is obtained by heating the hydroxide.

Uses

1. Used in Chemical Synthesis:
Germanium Dichloride-Dioxane Complex is used as a reagent in the chemical synthesis of various compounds due to its unique properties and reactivity. Its ability to act as both an acid and a base allows it to participate in a wide range of chemical reactions, making it a versatile compound in the field of chemistry.
2. Used in Semiconductor Industry:
In the semiconductor industry, Germanium Dichloride-Dioxane Complex is used as a precursor for the production of germanium-based semiconductor materials. Germanium is a key element in the manufacturing of certain types of transistors and other electronic components, and the complex serves as an important source of this element.
3. Used in Organic Synthesis:
Germanium Dichloride-Dioxane Complex is also utilized in organic synthesis as a catalyst or a reagent to facilitate specific reactions. Its unique properties enable it to promote the formation of desired products, making it a valuable tool in the synthesis of complex organic molecules.
4. Used in Analytical Chemistry:
In analytical chemistry, Germanium Dichloride-Dioxane Complex can be employed as a reference material or a standard for the calibration of analytical instruments. Its well-defined chemical properties and composition make it suitable for use in ensuring the accuracy and reliability of various analytical techniques.
5. Used in Research and Development:
Due to its unique chemical properties and potential applications, Germanium Dichloride-Dioxane Complex is often used in research and development settings. Scientists and researchers explore its properties and reactivity to discover new applications and improve existing ones, contributing to the advancement of various scientific fields.

Check Digit Verification of cas no

The CAS Registry Mumber 10060-11-4 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,0,0,6 and 0 respectively; the second part has 2 digits, 1 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 10060-11:
(7*1)+(6*0)+(5*0)+(4*6)+(3*0)+(2*1)+(1*1)=34
34 % 10 = 4
So 10060-11-4 is a valid CAS Registry Number.
InChI:InChI=1/Cl2Ge/c1-3-2

10060-11-4SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 18, 2017

Revision Date: Aug 18, 2017

1.Identification

1.1 GHS Product identifier

Product name dichlorogermanium

1.2 Other means of identification

Product number -
Other names Dichlorogermylene

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:10060-11-4 SDS

10060-11-4Synthetic route

diazoacetic acid ethyl ester
623-73-4

diazoacetic acid ethyl ester

Triethylgerman
1188-14-3

Triethylgerman

germaniumtetrachloride
10038-98-9

germaniumtetrachloride

phenylmagnesium bromide
100-58-3

phenylmagnesium bromide

A

germanium dichloride
10060-11-4

germanium dichloride

B

triethyl(phenyl)germane
2817-41-6

triethyl(phenyl)germane

C

tetraphenylgermane
1048-05-1

tetraphenylgermane

Conditions
ConditionsYield
In pentane byproducts: N2; 1 equiv of diazoester adding to a soln. of equimolar mixt. of Ge derivs., allowing to stand for 48 h at 20°C, orange-red oil decanting, PhMgBr adding to a supernatant; identified as adduct with ClCH2OMe;A 57%
B n/a
C n/a
germanium
7440-56-4

germanium

Iodine monochloride
7790-99-0

Iodine monochloride

A

germanium monochloride
21110-21-4

germanium monochloride

B

germanium dichloride
10060-11-4

germanium dichloride

Conditions
ConditionsYield
In gas Kinetics; metals were vaporized in a high temperature beam and the vapor were collimated upon entering a separatly pumped chamber filled with halogen; chemiluminescence spectroscopy;
germanium(II) sulfide

germanium(II) sulfide

lead(II) chloride

lead(II) chloride

germanium dichloride
10060-11-4

germanium dichloride

Conditions
ConditionsYield
excess of GeS;
germanium
7440-56-4

germanium

germaniumtetrachloride
10038-98-9

germaniumtetrachloride

germanium dichloride
10060-11-4

germanium dichloride

Conditions
ConditionsYield
350-400°C;
hexachlorodisilane
13465-77-5

hexachlorodisilane

germaniumtetrachloride
10038-98-9

germaniumtetrachloride

germanium dichloride
10060-11-4

germanium dichloride

Conditions
ConditionsYield
In neat (no solvent, gas phase) at 550°C; detn. by chemical trapping;
germanium hydride trichloride
1184-65-2

germanium hydride trichloride

germanium dichloride
10060-11-4

germanium dichloride

Conditions
ConditionsYield
byproducts: HCl; thermal decompn.;

10060-11-4Downstream Products

10060-11-4Relevant articles and documents

Jonkers, G.,Kerk, S. M. van der,Lange C. A. de

, p. 69 - 76 (1982)

ASSISTANCE NUCLEOPHILE DANS DES REACTIONS DE REDUCTION D'ORGANOHALOGENO- ET HALOGENO-GERMANES PAR DES REDUCTEURS DOUX R3M(IVB)-H ET RCHO: GERMYLANIONS, DERIVES FONCTIONNELS DU GERMANIUM

Castel, A.,Riviere, P.,Satge, J.

, p. 137 - 146 (2007/10/02)

Catalytic activity of nuclophiles such as tertiary amines and diazo derivatives in the reduction of halogermanes by means of gentle reductive agents, such as R3M(IVB)-H or RCHO, has been shown.In the particular case of enolisable aldehyde, a competition between nucleophilic substitution at the metal and germanium-halogen bond reduction has been observed.Transposition of enoxygermanes formed through the substitution process, leads to β-germylaldehydes.

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