100798-82-1

Basic information

• Product Name: N,N-diethyl 2-methyl-4-(diethylamino)butyramide
• Synonyms: N,N-diethyl 2-methyl-4-(diethylamino)butyramide
• CAS NO: 100798-82-1
• Molecular Weight: 228.378
• Mol File: 100798-82-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N,N-diethyl 2-methyl-4-(diethylamino)butyramide(CAS DataBase Reference)
• NIST Chemistry Reference: N,N-diethyl 2-methyl-4-(diethylamino)butyramide(100798-82-1)
• EPA Substance Registry System: N,N-diethyl 2-methyl-4-(diethylamino)butyramide(100798-82-1)

Safety Data

• Hazardous Substances Data: 100798-82-1(Hazardous Substances Data)

Upstream product

• 5441-99-6 N,N-diethylmethacrylamide 
• 201230-82-2 carbon monoxide 

Relevant articles and documents

Reactions of unsaturated amides under hydroformylation conditions

N,N-diethyl methacrylamide (1) undergoes hydroformylation, followed by subsequent reactions, under "oxo" conditions involving use of Rh4(CO)12 or Rh4(CO)12 in the presence of (R,R)-Diop (Diop = 2,2-dimethyl-1,3-dioxolane-4,5-diylbis (methylene)bis(diphenylphosphine)) as the catalyst precursor.The product first formed arises from formylation at the unsubstituted unsaturated carbon atom, and subsequently gives α-methyl-γ-butyrolactone (1b), N,N-diethyl 2-methyl-4-hydroxy-butyramide (1e), and N, N-diethyl 1-methyl-3-(diethylamino)butyramide (1f).Hydrogenation of the substrate takes also place.The product distribution can be strongly influenced by the reactions conditions.For N,N,N',N'-tetraethyl itacondiamide (2) under similar reactions conditions only hydrogenation and isomerization products are formed.