1008419-94-0Relevant articles and documents
The ionic introduction of an N1 unit to C60 and a unique rearrangement of aziridinofullerene
Minakata, Satoshi,Tsuruoka, Ryoji,Nagamachi, Toshiki,Komatsu, Mitsuo
, p. 323 - 325 (2008)
A new chloramine-based aziridination of C60 and unique rearrangement of aziridinofullerene to azafulleroid is described. The ionic introduction of an N1 unit to C60via an addition-cyclization mechanism was first achieved under mild conditions; the combination of chloramine and MS4A resulted in the promising rearrangement of aziridinofullerene to azafulleroid, and the isomerization could be performed catalytically. The Royal Society of Chemistry.