1008419-96-2Relevant articles and documents
Selective functionalization of fullerenes with N,N-dihalosulfonamides as an N1 unit: Versatile syntheses of aza[60]fulleroids and aziridino[60]fullerenes and their application to photovoltaic cells
Nagamachi, Toshiki,Takeda, Youhei,Nakayama, Kazuhisa,Minakata, Satoshi
supporting information, p. 12035 - 12045 (2012/10/30)
Highly selective and versatile methods for the synthesis of aza[60]fulleroids and aziridino[60]fullerenes from C60 have been developed. The reactions utilized N,N-dihalosulfonamides as an N1 source. The photophysical, electrochemical
The ionic introduction of an N1 unit to C60 and a unique rearrangement of aziridinofullerene
Minakata, Satoshi,Tsuruoka, Ryoji,Nagamachi, Toshiki,Komatsu, Mitsuo
, p. 323 - 325 (2008/09/19)
A new chloramine-based aziridination of C60 and unique rearrangement of aziridinofullerene to azafulleroid is described. The ionic introduction of an N1 unit to C60via an addition-cyclization mechanism was first achieved under mild conditions; the combination of chloramine and MS4A resulted in the promising rearrangement of aziridinofullerene to azafulleroid, and the isomerization could be performed catalytically. The Royal Society of Chemistry.