1025-09-8Relevant articles and documents
Corriu,Lanneau
, p. C63,C71,C72 (1974)
Synthesis of optically active tertiary silanes via Pd-catalyzed enantioselective arylation of secondary silanes
Kurihara, Yu,Nishikawa, Michihiro,Yamanoi, Yoshinori,Nishihara, Hiroshi
supporting information, p. 11564 - 11566 (2013/01/15)
We herein describe the development of an efficient enantioselective catalytic system that promotes the arylation of secondary silanes. Our method involves treatment of secondary silanes and aryl iodides with a Pd 2(dba)3-asymmetric p
A stereoselective approach to optically active bifunctional 1,3-dimethyl-1,3-diphenyldisiloxanes
Oishi, Motoi,Kawakami, Yusuke
, p. 549 - 551 (2008/02/12)
(Matrix presented) Functionalized disiloxanes have attracted much attention as versatile synthetic intermediates in the preparation of disiloxane-containing polymers. In this report, a highly stereoselective (98% inversion) halogenating cleavage reaction of the silicon-naphthyl bond to obtain optically active (S,S)-1,3-dimethyl-1,3-diphenyldisiloxanediol ((S,S):(R,S):(R,R) = 86:14:0) was demonstrated.