50881-11-3

Basic information

• Product Name: (R)-Methyl-naphthalen-1-yl-phenyl-propa-1,2-dienyl-silane
• CAS NO: 50881-11-3
• Molecular Weight: 286.448
• Mol File: 50881-11-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (R)-Methyl-naphthalen-1-yl-phenyl-propa-1,2-dienyl-silane(CAS DataBase Reference)
• NIST Chemistry Reference: (R)-Methyl-naphthalen-1-yl-phenyl-propa-1,2-dienyl-silane(50881-11-3)
• EPA Substance Registry System: (R)-Methyl-naphthalen-1-yl-phenyl-propa-1,2-dienyl-silane(50881-11-3)

Safety Data

• Hazardous Substances Data: 50881-11-3(Hazardous Substances Data)

Upstream product

• 60731-10-4 propadienylidene 
• 1025-09-8 (S)-methyl(naphthalen-1-yl)phenylsilane 

Relevant articles and documents

Axial Chirality by Asymmetric Induction. Diastereomeric Allene Formation via Silicon as a Chiral Auxiliary

Interaction of alkenylidenecarbenes, RCH=C=C:, R = CH3 and t-Bu, with chiral α-NpPhMeSi*H results in chiral allenes with a 3.5 +/- 0.5percent and 10.5 +/- 0.5percent diastereomeric excess, respectively.Hence the transfer of central chirality to axial chirality, via silicon as a chiral auxiliary, has been established.These results are discussed, and a transmission state is proposed.