1026466-52-3Relevant articles and documents
Nickel catalysis enables convergent paired electrolysis for direct arylation of benzylic C-H bonds
Hu, Xile,Zhang, Lei
, p. 10786 - 10791 (2020/10/26)
Convergent paired electrosynthesis is an energy-efficient approach in organic synthesis; however, it is limited by the difficulty to match the innate redox properties of reaction partners. Here we use nickel catalysis to cross-couple the two intermediates
Threefold and chemoselective couplings of triarylbismuths with benzylic chlorides and iodides using palladium catalysis
Rao, Maddali L. N.,Dhanorkar, Ritesh J.
, p. 13134 - 13144 (2014/04/03)
This paper describes the palladium-catalyzed studies on threefold coupling of triarylbismuth reagents with benzylic chlorides and iodides. The optimized protocol conditions are operationally simple, delivering threefold coupling of a variety of triarylbismuths in combination with benzylic chlorides and iodides. The two optimized protocols allowed the synthesis of a diverse range of unsymmetrical diarylmethanes in an efficient manner. As part of this study, chemoselective transformation of benzylic chlorides and iodides was also achieved. This journal is the Partner Organisations 2014.
Preparation of functionalized organoindium reagents by means of magnesium insertion into organic halides in the presence of InCl3 at room temperature
Bernhardt, Sebastian,Shen, Zhi-Liang,Knochel, Paul
supporting information, p. 828 - 833 (2013/02/23)
Magnesium, indium, palladium: An efficient one-pot procedure for the direct preparation of triorganoindium reagents from organic halides by means of magnesium insertion in the presence of InCl3 and LiCl is reported (see scheme). The organoindium reagents are obtained in good yields from functionalized aryl, heteroaryl, and alkyl bromides and benzyl chlorides at 25 °C in THF within 4h. Moreover, the resulting organoindium reagents could be efficiently used as reagents in Pd-catalyzed cross-coupling reactions with a wide functional group tolerance. Copyright