1027255-60-2

Basic information

• Product Name: methyl (E)-2-(3-phenylprop-1-en-1-yl)benzoate
• Synonyms: methyl (E)-2-(3-phenylprop-1-en-1-yl)benzoate
• CAS NO: 1027255-60-2
• Molecular Weight: 252.313
• Mol File: 1027255-60-2.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: methyl (E)-2-(3-phenylprop-1-en-1-yl)benzoate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl (E)-2-(3-phenylprop-1-en-1-yl)benzoate(1027255-60-2)
• EPA Substance Registry System: methyl (E)-2-(3-phenylprop-1-en-1-yl)benzoate(1027255-60-2)

Safety Data

• Hazardous Substances Data: 1027255-60-2(Hazardous Substances Data)

Upstream product

• 610-94-6 2-bromobenzoic acid methyl ester 
• 177573-86-3 (E)-4,4,5,5-tetramethyl-2-(3-phenylprop-1-en-1-yl)-1,3,2-dioxaborolane 
• 60494-73-7 (2-methoxycarbonylbenzyl)triphenylphosphonium bromide 
• 122-78-1 phenylacetaldehyde 

Downstream Products

• 164988-57-2 2-(3-phenyl-propyl)-benzoyl chloride 
• 13203-90-2 2-(3-Phenylpropyl)benzoic acid 

Relevant articles and documents

Enantioselective, Catalytic Fluorolactonization Reactions with a Nucleophilic Fluoride Source

The enantioselective synthesis of 4-fluoroisochromanones via chiral aryl iodide-catalyzed fluorolactonization is reported. This methodology uses HF-pyridine as a nucleophilic fluoride source with a peracid stoichiometric oxidant and provides access to lactones containing fluorine-bearing stereogenic centers in high enantio- and diastereoselectivity. The regioselectivity observed in these lactonization reactions is complementary to that obtained with established asymmetric electrophilic fluorination protocols.