1032189-92-6Relevant articles and documents
Combined metalation-cross coupling strategies: A synthesis of schumanniophytine by a key biaryl O-carbamate remote anionic fries rearrangement
Macklin, Todd K.,Reed, Mark A.,Snieckus, Victor
supporting information; scheme or table, p. 1507 - 1509 (2009/04/11)
A short synthesis of the alkaloid schumanniophytine (1) starting from simple building blocks and involving directed ortho metalation (DoM), Suzuki-Miyaura cross coupling, and a key ortho-silicon-induced O-carbamate remote anionic Fries rearrangement (3) is described. Wiley-VCH Verlag GmbH & Co. KGaA, 2008.