10381-68-7

Basic information

• Product Name: Benzene, 1-methyl-2-[(4-methylphenyl)sulfinyl]-
• Synonyms: opt.-akt. o-Tolyl-p-tolyl-sulfoxid
• CAS NO: 10381-68-7
• Molecular Formula: C14H14OS
• Molecular Weight: 230.331
• Mol File: 10381-68-7.mol
• Article Data: 6

Chemical Properties

• Melting Point: 90 °C
• Boiling Point: 210 °C(Press: 9 Torr)
• Density: 1.19±0.1 g/cm3(Predicted)
• CAS DataBase Reference: Benzene, 1-methyl-2-[(4-methylphenyl)sulfinyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-methyl-2-[(4-methylphenyl)sulfinyl]-(10381-68-7)
• EPA Substance Registry System: Benzene, 1-methyl-2-[(4-methylphenyl)sulfinyl]-(10381-68-7)

Safety Data

• Hazardous Substances Data: 10381-68-7(Hazardous Substances Data)

Upstream product

• 1858-86-2 Ethyl p-toluenesulfinate 
• 95-46-5 2-methylphenyl bromide 
• 932-31-0 ortho-tolylmagnesium bromide 
• 1517-82-4 (-)-menthyl p-toluenesulfinate 
• 94626-19-4 2-methylbenzenesulfinic acid methyl ester 
• 5720-05-8 4-methylphenylboronic acid 
• 108-88-3 toluene 
• 71-43-2 benzene 
• 4279-70-3 (2?methylphenyl)(4?methylphenyl) sulfide 
• 10381-68-7 (S)-2-methyl-1-(p-tolylsulfinyl)benzene 

Downstream Products

• 835626-69-2 (S)-{3-[2-(p-tolylsulfinyl)phenyl]propoxy}triisopropylsilane 
• 950829-01-3 (1S)-N-(4-methoxyphenyl)-1-phenyl-2-{2-[(S)-p-tolylsulfinyl]phenyl}ethylamine 
• 950829-02-4 (1R)-N-(4-methoxyphenyl)-1-phenyl-2-{2-[(S)-p-tolylsulfinyl]phenyl}ethylamine 

Relevant articles and documents

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Palladium-Catalyzed Sulfinylation of Aryl- And Alkenylborons with Sulfinate Esters

An efficient, direct sulfinylation of organoborons catalyzed by palladium is disclosed. Treatment of organoborons and sulfinate esters in the presence of a palladium precatalyst provided a broad range of sulfoxides. Various organosulfur compounds having oxidizable functional groups were successfully prepared through the sulfoxide synthesis.

Synthesis of enantiomerically pure 1,2-disubstituted 2-selenoamines

Optically pure phenylseleno-(S)-2-p-tolylsulfinylbenzylcarbanions react with (S)-N-2-p-tolylsulfinylimines derived from aliphatic and aromatic aldehydes in a highly stereoselective manner affording bis-sulfinylselenoamines, easily transformed into 1-pheny