104637-14-1

Basic information

• Product Name: (3R,4E)-4,6-diphenylhex-5-en-2-one
• Synonyms: (3R,4E)-4,6-diphenylhex-5-en-2-one
• CAS NO: 104637-14-1
• Molecular Weight: 250.34
• Mol File: 104637-14-1.mol
• Article Data: 19

Chemical Properties

• CAS DataBase Reference: (3R,4E)-4,6-diphenylhex-5-en-2-one(CAS DataBase Reference)
• NIST Chemistry Reference: (3R,4E)-4,6-diphenylhex-5-en-2-one(104637-14-1)
• EPA Substance Registry System: (3R,4E)-4,6-diphenylhex-5-en-2-one(104637-14-1)

Safety Data

• Hazardous Substances Data: 104637-14-1(Hazardous Substances Data)

Upstream product

• 65119-09-7 (E)-styryl(triethoxy)silane 
• 1896-62-4 (E)-benzalacetone 
• 536-74-3 phenylacetylene 
• 87751-69-7 rac-(E)-1,3-diphenyl-3-acetoxy-prop-1-ene 
• 67-64-1 acetone 
• 98-80-6 phenylboronic acid 
• 541-50-4 2-acetoacetic acid 
• 62668-02-4 (E)-1,3-diphenyl-2-propen-1-ol 
• 191542-57-1 ethyl 3-oxo-2-((E)-1,3-diphenyl-2-propenyl)butanoate 
• 6783-05-7 trans-2-phenylvinylboronic acid 
• 122-57-6 1-Phenylbut-1-en-3-one 
• 100-52-7 benzaldehyde 
• 1833-53-0 2-(Trimethylsilyloxy)propene 
• 121440-72-0 (E)-1,3-diphenylallyl methyl carbonate 

Downstream Products

• 74457-44-6 (S)-methyl 4-oxo-2-phenylpentanoate 

Relevant articles and documents

Asymmetric allylic alkylation of ketone enolates: An asymmetric claisen surrogate

(Chemical Equation Presented) The combination of catalytic palladium(0) and Trost ligand provides an effective catalyst for the rearrangement of allyl β-ketoesters. The mechanism of the transformation involves formation of π-allyl palladium intermediates which undergo enantioselective attack by ketone enolates. Decarboxylation of β-ketocarboxylates allows regiospecific generation of enolates under extremely mild conditions.

Decarboxylative substitution of β-keto acids to benzylic alcohols catalyzed by molecular iodine

An efficient method for molecular iodine catalyzed decarboxylative substitution of β-keto acids with benzylic alcohols under mild conditions has been described and valuable α-functionalized ketones were obtained in good to excellent yields.

Ruthenium-catalyzed decarboxylative allylation of nonstabilized ketone enolates

(Matrix Presented) Bipyridyl(pentamethylcyclopentadienyl)ruthenium chloride is an efficient catalyst for the formal [3,3] rearrangement of allyl β-ketoesters. The mechanism of the transformation involves formation of π-allyl ruthenium intermediates, which

Method for synthesizing optical activity ketones compound through asymmetric conjugate addition reaction of organic boric acid and Alpha,Beta-unsaturated ketone

The invention discloses a method for synthesizing an optical activity ketones compound through an asymmetric conjugate addition reaction of an organic boric acid and an Alpha,Beta-unsaturated ketone,and belongs to the technical field of the asymmetric syn