87751-69-7

Basic information

• Product Name: (±)-trans-1,3-Diphenylallyl acetate
• Synonyms: (±)-trans-1,3-Diphenylallyl acetate;(+/-)-trans-1,3-Diphenylallyl acetate 97%;Acetic acid trans-1,3-diphenylallyl ester
• CAS NO: 87751-69-7
• Molecular Formula: C₁₇H₁₆O₂
• Molecular Weight: 252.30774
• Mol File: 87751-69-7.mol
• Article Data: 28

Chemical Properties

• Appearance: /
• BRN: 3610772
• CAS DataBase Reference: (±)-trans-1,3-Diphenylallyl acetate(CAS DataBase Reference)
• NIST Chemistry Reference: (±)-trans-1,3-Diphenylallyl acetate(87751-69-7)
• EPA Substance Registry System: (±)-trans-1,3-Diphenylallyl acetate(87751-69-7)

Safety Data

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26
• WGK Germany: 3
• Hazardous Substances Data: 87751-69-7(Hazardous Substances Data)

Usage

General Description

(±)-trans-1,3-Diphenylallyl acetate is a chemical compound with the molecular formula C18H16O2. It is a chiral compound, meaning it has two mirror-image forms, and is commonly used in organic synthesis. This chemical is a type of allyl acetate, a compound with a double bond between carbon atoms. It is often used as a starting material in reactions to synthesize other organic compounds. Its unique structure and reactivity make it a valuable building block in the production of various pharmaceuticals, fragrances, and other specialty chemicals. Additionally, (±)-trans-1,3-Diphenylallyl acetate is also used as a flavoring agent and aroma compound in the food and beverage industry. Overall, this compound plays an important role in both scientific research and commercial applications.

Upstream product

• 14371-10-9 (E)-3-phenylpropenal 
• 108-24-7 acetic anhydride 
• 100-58-3 phenylmagnesium bromide 
• 62668-02-4 (E)-1,3-diphenyl-2-propen-1-ol 
• 108-22-5 Isopropenyl acetate 
• 75-36-5 acetyl chloride 
• 4663-33-6 1,3-diphenyl-3-hydroxypropene 
• 108-86-1 bromobenzene 
• 614-47-1 1,3-diphenyl-propen-3-one 
• 104-55-2 3-phenyl-propenal 
• 64847-78-5 (E)-1,1-diacetoxy-3-phenylprop-2-ene 
• 591-50-4 iodobenzene 
• 7217-71-2 1-phenyl-2-propenyl acetate 
• 98-80-6 phenylboronic acid 

Downstream Products

• 136859-93-3 (S)-1',1'-dimethylethyl 2-carbo-1'',1''-dimethylethoxy-3,5-diphenylpent-4-enoate 
• 136859-93-3 (R)-1',1'-dimethylethyl 2-carbo-1'',1''-dimethylethoxy-3,5-diphenylpent-4-enoate 
• 136859-90-0 2-Benzyl-2-((E)-1,3-diphenyl-allyl)-malonic acid dimethyl ester 
• 95071-02-6 (R)-methyl 2-carbomethoxy-3,5-diphenylpent-4-enoate 
• 177468-91-6 (E)-dimethyl (1,3-diphenylprop-2-en-1-yl)propanedioate 
• 95071-02-6 dimethyl 2-[(E)-(S)-1,3-diphenylallyl]-malonate 
• 18916-14-8 trans-prop-2-ene-1,1,3-triyltribenzene 
• 130866-13-6 (E)-2-(Diethoxy-phosphoryl)-3,5-diphenyl-pent-4-enoic acid ethyl ester 
• 136859-91-1 2-((E)-(R)-1,3-Diphenyl-allyl)-2-(2,2,2-trifluoro-acetylamino)-malonic acid dimethyl ester 
• 136859-91-1 2-((E)-(S)-1,3-Diphenyl-allyl)-2-(2,2,2-trifluoro-acetylamino)-malonic acid dimethyl ester 
• 204578-86-9 ((1E,5E)-hexa-1,5-diene-1,3,4,6-tetrayl)tetrabenzene 
• 3412-44-0 (1E)-1,3-diphenylpropene 
• 121440-78-6 (E)-N-(1,3-diphenyl-1λ³-allyl)-4-methylbenzenesulfonamide 
• 119477-58-6 (E)-(S)-2-Acetyl-3,5-diphenyl-pent-4-enoic acid methyl ester 

Relevant articles and documents

Pd-Catalyzed Nazarov-Type Cyclization: Application in the Total Synthesis of β-Diasarone and Other Complex Cyclopentanoids

We describe the palladium-catalyzed Nazarov-type cyclization of easily accessible (hetero)arylallyl acetates to pentannulated (hetero)arenes. This method provides ready access to various types of bi-, tri-, tetra-, and pentacyclic cyclopentanoids under ne

Carbamate-based P,O-ligands for asymmetric allylic alkylations

Herein we report the design and successful catalytic application of modified Trost-ligands in asymmetric allylic alkylation (AAA) reactions. A small set of carbamate-monophosphine P,O-ligands has been prepared in a straightforward two-step synthetic procedure. After optimization of the reaction conditions, high catalytic activities and excellent enantioselectivity up to >99% have been attained.

METHODS AND COMPOSITIONS FOR SUBSTITUTED ARYLCYCLOHEPTANE ANALOGS

In one aspect, the disclosure relates to methods for preparation of intermediates useful for the preparation of aryl-cycloheptene scaffolds. In a further aspect, the disclosed methods pertain to the preparation of compounds comprising an aryl-cycloheptene