64847-78-5

Basic information

• Product Name: 2-Propene-1,1-diol, 3-phenyl-, diacetate
• CAS NO: 64847-78-5
• Molecular Formula: C13H14O4
• Molecular Weight: 234.252
• Mol File: 64847-78-5.mol
• Article Data: 114

Chemical Properties

• CAS DataBase Reference: 2-Propene-1,1-diol, 3-phenyl-, diacetate(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Propene-1,1-diol, 3-phenyl-, diacetate(64847-78-5)
• EPA Substance Registry System: 2-Propene-1,1-diol, 3-phenyl-, diacetate(64847-78-5)

Safety Data

• Hazardous Substances Data: 64847-78-5(Hazardous Substances Data)

Upstream product

• 104-55-2 3-phenyl-propenal 
• 869-29-4 1,1-diacetoxy-2-propene 
• 66003-76-7 Diphenyliodonium triflate 
• 14371-10-9 (E)-3-phenylpropenal 
• 108-24-7 acetic anhydride 
• 62-38-4 phenylmercury(II)acetate 
• 103-54-8 cinnamyl acetate 
• 64-19-7 acetic acid 
• 300-57-2 allylbenzene 
• 7664-93-9 sulfuric acid 

Downstream Products

• 97509-88-1 2-((E)-1-Acetoxy-3-phenyl-allyl)-2-(3,3-bis-benzenesulfonyl-propyl)-malonic acid dimethyl ester 
• 104-55-2 3-phenyl-propenal 
• 36713-66-3 3-phenylheptanal 
• 120126-99-0 1-[(E)-2-phenylvinyl]but-3-enyl acetate 
• 26958-41-8 cinnamyl-1,3-dithiane 
• 5616-58-0 2-styryl-1,3-dithiolane 
• 95745-36-1 3,3'-bisindolyl-1-(2-phenylethylene)methane 
• 80006-88-8 (1E)-1-phenyl-1-hepten-3-yl acetate 
• 87751-69-7 rac-(E)-1,3-diphenyl-3-acetoxy-prop-1-ene 
• 849-01-4 1,3,3-triphenylprop-2-en-1-one 
• 5424-75-9 prop-2-ene-1,1,3-triyltribenzene 
• 4407-36-7 (2E)-3-phenyl-2-propen-1-ol 

Relevant articles and documents

The studies on chemoselective promiscuous activity of hydrolases on acylals transformations

Chemoselective, mild and convenient protocol for the hydrolysis of the synthetically relevant acylals via promiscuous enzyme-catalyzed hydrolysis has been developed. It has been shown that promiscuous activity of the used hydrolases dominates their native activity related with carboxylic esters hydrolysis. The main advantage of the present methodology is that it can be conducted under neutral conditions at room temperature. Moreover, complete deprotection of acylals takes place within 10–20 min. Developed protocol can be used with compounds having a variety of hydrolytic labile groups since the cleavage is proceeded under neutral conditions and occurs exclusively on acylal moiety. Further this protocol was extended by the tandem Passerini multicomponent reaction leading to the α-acetoxy amides using acylals as the surrogates of the carbonyl components to P-MCR.

Supported N-propylsulfamic acid onto Fe3O4 magnetic nanoparticles as a reusable and efficient nanocatalyst for the protection/deprotection of hydroxyl groups and protection of aldehydes

N-propylsulfamic acid supported onto Fe3O4 magnetic nanoparticles (MNPs-PSA) as an efficient and magnetically reusable nanocatalyst has been reported for the tetrahydropyranylation/depyranylation of a wide variety of alcohols and phenols by changing the solvent medium. Also, the protection of aldehydes as acylals using Ac2O in the presence of catalytic amount MNPs-PSA in good to high yields at room temperature under solvent-free conditions is described. After completing the reaction, the catalyst was easily separated from the reaction mixture with the assistance of an external magnetic field and reused for several consecutive runs without significant loss of their catalytic efficiency.

Preparation of 1,1-diacetates from aldehydes by LiBH4 and Ac2O in the presence of cation exchange resin

A variety of 1,1-diacetates have been produced from the corresponding aldehydes (1 mmol) by LiBH4(1.25 mmol) and Ac2O (1 mL) in the presence of DOWEX(R)50WX4 (0.5 g) as a cation exchange resinwithin 10 min at room temperature with excellent yields of the products (93-97%).