130866-13-6

Basic information

• Product Name: (E)-2-(Diethoxy-phosphoryl)-3,5-diphenyl-pent-4-enoic acid ethyl ester
• CAS NO: 130866-13-6
• Molecular Weight: 416.454
• Mol File: 130866-13-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (E)-2-(Diethoxy-phosphoryl)-3,5-diphenyl-pent-4-enoic acid ethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-2-(Diethoxy-phosphoryl)-3,5-diphenyl-pent-4-enoic acid ethyl ester(130866-13-6)
• EPA Substance Registry System: (E)-2-(Diethoxy-phosphoryl)-3,5-diphenyl-pent-4-enoic acid ethyl ester(130866-13-6)

Safety Data

• Hazardous Substances Data: 130866-13-6(Hazardous Substances Data)

Upstream product

• 87751-69-7 rac-(E)-1,3-diphenyl-3-acetoxy-prop-1-ene 

Relevant articles and documents

The first synthesis of chiral phosphinocarboxylic acid ligands, trans-2-(diphenylphosphino) cycloalkanecarboxylic acids. The phosphine-palladium complexes catalyzed asymmetric allylic alkylation

The first synthesized chiral phosphinocarboxylic acids were effective as ligand for the palledium-catalyzed asymmetric allylic alkylation of 3-acetoxy-1,3-diphenyl-1-propene and 2-cyclohexenyl acetate with soft carbanion from dimethyl malonate or triethyl phosphonoacetate and sodium hydride to give the alkylation products of up to 83% ee.